CHIMIVER PANSERI S.p.A. ADESIVER RE 400 RF
Revision nr.7 Dated 26/05/2021 Printed on 24/01/2022 Page n. 1 / 9 Replaced revision:6 (Dated 26/05/2021)
Safety Data Sheet According to Annex II to REACH - Regulation (EU) 2015/830
SECTION 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier
ADESIVER RE 400 RF
Product name
1.2. Relevant identified uses of the substance or mixture and uses advised against
Water-based fire-retardant adhesive
Intended use
1.3. Details of the supplier of the safety data sheet
CHIMIVER PANSERI S.p.A.
Name
Via Bergamo 1401
Full address
24030
PONTIDA
(BG)
District and Country
ITALIA
+39 035 795031 +39 035 795556
Tel. Fax
e-mail address of the competent person responsible for the Safety Data Sheet
msds@chimiver.com
1.4. Emergency telephone number
For urgent inquiries refer to
Poison centers: - Milano 02 66101029 (Osp. Niguarda Ca' Granda) - Bergamo 800 883300 (Azienda Ospedaliera Papa Giovanni XXII) - Verona 800 011858 (Azienda Ospedaliera Integrata) - Pavia 0382 24444 (CAV Centro Nazionale di Informazione Tossicologica) - Firenze 055 7947819 (Az. Osp. "Careggi" U.O. Tossicologia Medica) - Roma 06 3054343 (CAV Policlinico "A. Gemelli" ) - Roma 06 68593726 (CAV “Osp. Pediatrico Bambino Gesù”)
- Roma 06 49978000 (CAV Policlinico "Umberto I") - Napoli 081 5453333 (Az. Osp. "A. Cardarelli") - Foggia 800 183459 (Az. Osp. Univ. Foggia)
SECTION 2. Hazards identification 2.1. Classification of the substance or mixture The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments and supplements). Hazard classification and indication: --
2.2. Label elements
Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements.
Hazard pictograms:
--
Signal words:
--
Hazard statements: EUH210
Safety data sheet available on request.
EUH208
Contains:
Mixture of: 5-chloro-2-methyl-2H-isothiazol-3-one; 2-methyl-2H-isothiazol-3-one (3: 1) 1,2-benzisothiazol-3(2H)-one
May produce an allergic reaction.
Precautionary statements:
--
EPY 10.5.2 - SDS 1004.14
CHIMIVER PANSERI S.p.A. ADESIVER RE 400 RF
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SECTION 2. Hazards identification
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2.3. Other hazards
On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%.
SECTION 3. Composition/information on ingredients 3.2. Mixtures
The product does not contain substances classified as being hazardous to human health or the environment pursuant to the provisions Regulation (EC) 1272/2008 (CLP) (and subsequent amendments and supplements) in such quantities as to require the statement. SECTION 4. First aid measures 4.1. Description of first aid measures EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 30-60 minutes, opening the eyelids fully. Get medical advice/attention. SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention. INGESTION: Have the subject drink as much water as possible. Get medical advice/attention. Do not induce vomiting unless explicitly authorised by a doctor. INHALATION: Get medical advice/attention immediately. Remove victim to fresh air, away from the accident scene. If the subject stops breathing, administer artificial respiration. Take suitable precautions for rescue workers.
4.2. Most important symptoms and effects, both acute and delayed
Specific information on symptoms and effects caused by the product are unknown.
4.3. Indication of any immediate medical attention and special treatment needed
Information not available
SECTION 5. Firefighting measures 5.1. Extinguishing media
SUITABLE EXTINGUISHING EQUIPMENT The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. UNSUITABLE EXTINGUISHING EQUIPMENT None in particular.
5.2. Special hazards arising from the substance or mixture
HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE Do not breathe combustion products.
5.3. Advice for firefighters
GENERAL INFORMATION Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated water used for extinction and the remains of the fire according to applicable regulations. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). SECTION 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Block the leakage if there is no hazard. Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency procedures.
6.2. Environmental precautions
The product must not penetrate into the sewer system or come into contact with surface water or ground water.
EPY 10.5.2 - SDS 1004.14
CHIMIVER PANSERI S.p.A. ADESIVER RE 400 RF
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SECTION 6. Accidental release measures
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6.3. Methods and material for containment and cleaning up
Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the remainder with inert absorbent material. Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13.
6.4. Reference to other sections
Any information on personal protection and disposal is given in sections 8 and 13.
SECTION 7. Handling and storage 7.1. Precautions for safe handling
Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the environment. Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering places in which people eat.
7.2. Conditions for safe storage, including any incompatibilities
Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away from any incompatible materials, see section 10 for details.
7.3. Specific end use(s)
Information not available
SECTION 8. Exposure controls/personal protection 8.1. Control parameters
Information not available
8.2. Exposure controls
As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well aired through effective local aspiration.
When choosing personal protective equipment, ask your chemical substance supplier for advice. Personal protective equipment must be CE marked, showing that it complies with applicable standards. HAND PROTECTION Protect hands with category III work gloves (see standard EN 374).
The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on the duration and type of use. SKIN PROTECTION Wear category I professional long-sleeved overalls and safety footwear (see Regulation 2016/425 and standard EN ISO 20344). Wash body with soap and water after removing protective clothing. EYE PROTECTION Wear airtight protective goggles (see standard EN 166). RESPIRATORY PROTECTION If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type A filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the threshold values considered. The protection provided by masks is in any case limited. If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529. ENVIRONMENTAL EXPOSURE CONTROLS The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure compliance with environmental standards.
EPY 10.5.2 - SDS 1004.14
CHIMIVER PANSERI S.p.A. ADESIVER RE 400 RF
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SECTION 9. Physical and chemical properties
9.1. Information on basic physical and chemical properties
Properties Appearance
Value paste ivory
Information
Colour Odour
characteristic Not available Not available Not available Not available Not available 60 °C Not available Not available Not available Not available Not available Not available Not available Not available Not available Not available Not available Not available Not available Not available Not available 1,28
Odour threshold
pH
Melting point / freezing point
Initial boiling point Boiling range Flash point Evaporation rate
>
Flammability of solids and gases Lower inflammability limit Upper inflammability limit
Lower explosive limit Upper explosive limit Vapour pressure
Vapour density Relative density
Solubility
Partition coefficient: n-octanol/water
Auto-ignition temperature Decomposition temperature
Viscosity
Explosive properties Oxidising properties
9.2. Other information
VOC (Directive 2010/75/EU) :
0,03 % - 0,35
g/litre
SECTION 10. Stability and reactivity 10.1. Reactivity
There are no particular risks of reaction with other substances in normal conditions of use.
10.2. Chemical stability
The product is stable in normal conditions of use and storage.
10.3. Possibility of hazardous reactions
No hazardous reactions are foreseeable in normal conditions of use and storage.
10.4. Conditions to avoid
None in particular. However the usual precautions used for chemical products should be respected.
10.5. Incompatible materials
Information not available
10.6. Hazardous decomposition products
Information not available
SECTION 11. Toxicological information In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it contains, using the criteria specified in the applicable regulation for classification. It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the
EPY 10.5.2 - SDS 1004.14
CHIMIVER PANSERI S.p.A. ADESIVER RE 400 RF
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SECTION 11. Toxicological information
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toxicological effects of exposure to the product.
11.1. Information on toxicological effects
Metabolism, toxicokinetics, mechanism of action and other information
Information not available
Information on likely routes of exposure
Information not available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Information not available
Interactive effects
Information not available
ACUTE TOXICITY
ATE (Inhalation) of the mixture: ATE (Oral) of the mixture: ATE (Dermal) of the mixture:
Not classified (no significant component) Not classified (no significant component) Not classified (no significant component)
SKIN CORROSION / IRRITATION
Does not meet the classification criteria for this hazard class
SERIOUS EYE DAMAGE / IRRITATION
Does not meet the classification criteria for this hazard class
RESPIRATORY OR SKIN SENSITISATION
May produce an allergic reaction. Contains: Mixture of: 5-chloro-2-methyl-2H-isothiazol-3-one; 2-methyl-2H-isothiazol-3-one (3: 1) 1,2-benzisothiazol-3(2H)-one
GERM CELL MUTAGENICITY
Does not meet the classification criteria for this hazard class
CARCINOGENICITY
Does not meet the classification criteria for this hazard class
REPRODUCTIVE TOXICITY
Does not meet the classification criteria for this hazard class
STOT - SINGLE EXPOSURE
Does not meet the classification criteria for this hazard class
STOT - REPEATED EXPOSURE
Does not meet the classification criteria for this hazard class
ASPIRATION HAZARD
Does not meet the classification criteria for this hazard class
EPY 10.5.2 - SDS 1004.14
CHIMIVER PANSERI S.p.A. ADESIVER RE 400 RF
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SECTION 12. Ecological information Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or contaminate soil or vegetation.
12.1. Toxicity
Information not available
12.2. Persistence and degradability
Information not available
12.3. Bioaccumulative potential
Information not available
12.4. Mobility in soil
Information not available
12.5. Results of PBT and vPvB assessment
On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%.
12.6. Other adverse effects
Information not available
SECTION 13. Disposal considerations 13.1. Waste treatment methods
Reuse, when possible. Neat product residues should be considered special non-hazardous waste. Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. CONTAMINATED PACKAGING Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. SECTION 14. Transport information The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations.
14.1. UN number
Not applicable
14.2. UN proper shipping name
Not applicable
14.3. Transport hazard class(es)
Not applicable
14.4. Packing group
Not applicable
EPY 10.5.2 - SDS 1004.14
CHIMIVER PANSERI S.p.A. ADESIVER RE 400 RF
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SECTION 14. Transport information
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14.5. Environmental hazards
Not applicable
14.6. Special precautions for user
Not applicable
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Information not relevant
SECTION 15. Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Seveso Category - Directive 2012/18/EU:
None
Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006 Contained substance 75 Point 1,2-benzisothiazol-3(2H)-one 75 Point
Mixture of: 5-chloro-2-methyl-2H-isothiazol-3-one; 2-methyl-2H-isothiazol-3-one (3: 1)
Regulation (EU) 2019/1148 - on the marketing and use of explosives precursors Not applicable
Substances in Candidate List (Art. 59 REACH) On the basis of available data, the product does not contain any SVHC in percentage ≥ than 0,1%. Substances subject to authorisation (Annex XIV REACH) None Substances subject to exportation reporting pursuant to Regulation (EU) 649/2012: None Substances subject to the Rotterdam Convention: None Substances subject to the Stockholm Convention: None
Healthcare controls Information not available
15.2. Chemical safety assessment
A chemical safety assessment has not been performed for the preparation/for the substances indicated in section 3.
SECTION 16. Other information Text of hazard (H) indications mentioned in section 2-3 of the sheet:
EUH210
Safety data sheet available on request.
LEGEND: - ADR: European Agreement concerning the carriage of Dangerous goods by Road - CAS: Chemical Abstract Service Number
- CE50: Effective concentration (required to induce a 50% effect) - CE: Identifier in ESIS (European archive of existing substances)
- CLP: Regulation (EC) 1272/2008 - DNEL: Derived No Effect Level - EmS: Emergency Schedule
- GHS: Globally Harmonized System of classification and labeling of chemicals - IATA DGR: International Air Transport Association Dangerous Goods Regulation - IC50: Immobilization Concentration 50% - IMDG: International Maritime Code for dangerous goods
EPY 10.5.2 - SDS 1004.14
CHIMIVER PANSERI S.p.A. ADESIVER RE 400 RF
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SECTION 16. Other information
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- IMO: International Maritime Organization - INDEX: Identifier in Annex VI of CLP - LC50: Lethal Concentration 50% - LD50: Lethal dose 50% - OEL: Occupational Exposure Level - PBT: Persistent bioaccumulative and toxic as REACH Regulation - PEC: Predicted environmental Concentration - PEL: Predicted exposure level - PNEC: Predicted no effect concentration - REACH: Regulation (EC) 1907/2006 - RID: Regulation concerning the international transport of dangerous goods by train - TLV: Threshold Limit Value - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. - TWA: Time-weighted average exposure limit
- TWA STEL: Short-term exposure limit - VOC: Volatile organic Compounds - vPvB: Very Persistent and very Bioaccumulative as for REACH Regulation - WGK: Water hazard classes (German).
GENERAL BIBLIOGRAPHY 1. Regulation (EC) 1907/2006 (REACH) of the European Parliament 2. Regulation (EC) 1272/2008 (CLP) of the European Parliament 3. Regulation (EC) 790/2009 (I Atp. CLP) of the European Parliament 4. Regulation (EU) 2015/830 of the European Parliament 5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament 6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament 7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament 8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament 9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament 10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament 11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament
12. Regulation (EU) 2016/1179 (IX Atp. CLP) 13. Regulation (EU) 2017/776 (X Atp. CLP) 14. Regulation (EU) 2018/669 (XI Atp. CLP) 15. Regulation (EU) 2018/1480 (XIII Atp. CLP) 16. Regulation (EU) 2019/521 (XII Atp. CLP) 17. Regulation (EU) 2019/1148 18. Regulation (EU) 2020/217 (XIV Atp. CLP)
- The Merck Index. - 10th Edition - Handling Chemical Safety - INRS - Fiche Toxicologique (toxicological sheet) - Patty - Industrial Hygiene and Toxicology - N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition - IFA GESTIS website - ECHA website - Database of SDS models for chemicals - Ministry of Health and ISS (Istituto Superiore di Sanità) - Italy
Note for users: The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability and thoroughness of provided information according to each specific use of the product. This document must not be regarded as a guarantee on any specific product property. The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health and safety laws and regulations. The producer is relieved from any liability arising from improper uses. Provide appointed staff with adequate training on how to use chemical products. CALCULATION METHODS FOR CLASSIFICATION Chemical and physical hazards: Product classification derives from criteria established by the CLP Regulation, Annex I, Part 2. The data for evaluation of chemical-physical properties are reported in section 9. Health hazards: Product classification is based on calculation methods as per Annex I of CLP, Part 3, unless determined otherwise in Section 11. Environmental hazards: Product classification is based on calculation methods as per Annex I of CLP, Part 4, unless determined otherwise in Section 12.
Changes to previous review:
EPY 10.5.2 - SDS 1004.14
CHIMIVER PANSERI S.p.A. ADESIVER RE 400 RF
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SECTION 16. Other information
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The following sections were modified: 09.
EPY 10.5.2 - SDS 1004.14
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