Mechanical-Integrity_Booklet_2025_V4 DIGITAL

939-D Stress Corrosion Cracking of Carbon Steel in Fuel Grade Ethanol— Review, Experience Survey, Field Monitoring, and Laboratory Testing Discusses stress corrosion cracking (SCC) of carbon steel tanks, piping, and equipment exposed to fuel ethanol as a consequence of being in the distribution system, at ethanol distribution facilities, or end user (EU) facilities where the fuel ethanol is eventually added to gasoline. Such equipment includes but is not limited to storage tanks, piping and related handling equipment, and pipelines that are used in distribution, handling, storage, and blending of fuel ethanol. However, data for pipelines in ethanol service is limited and caution should be used when applying guidelines from this document that have been derived mainly from applications involving piping and tanks in ethanol storage and blending facilities. SCC of other metals and alloys is beyond the scope of this document, as is the corrosion of steel in this service. API RP 941 Steels for Hydrogen Service at Elevated Temperatures and Pressures in Petroleum Refineries and Petrochemical Plants Summarizes the results of experimental tests and actual data acquired from operating plants to establish practical operating limits for carbon and low alloy steels in hydrogen service at elevated temperatures and pressures. The effects on the resistance of steels to hydrogen at elevated temperature and pressure that result from high stress, heat treating, chemical composition, and cladding are discussed. This recommended practice (RP) does not address the resistance of steels to hydrogen at lower temperatures [below about 400 °F (204 °C)], where atomic hydrogen enters the steel as a result of an electrochemical mechanism. This RP applies to equipment in refineries, petrochemical facilities, and chemical facilities in which hydrogen or hydrogen-containing fluids are processed at elevated temperature and pressure. The guidelines in this RP can also be applied to hydrogenation plants such as those that manufacture ammonia, methanol, edible oils, and higher alcohols.

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