PAPERmaking! Vol10 Nr3 2024

Störmer et al.

10.3389/fchem.2024.1397913

Funding

if yes, then at which level. From a legal compliance point of view, harsh and very severe time – temperature conditions can be selected, but the results are likely to allow only proving but not disapproving compliance and therefore unnecessarily disqualify paper food contact materials. Estimation of exposure would fail anyway. Aspect (ii): Out of the different modeling approaches, a physical – chemical model based on the knowledge of the underlying mass transport mechanisms and processes, as well as on the determining parameters, such as diffusion constants and partition coef fi cients, are, in our opinion, the most promising and sustainable approach. However, there is a lack of qualitative and quantitative understanding of the factors and determinants of transport and partitioning processes in and from paper. For compliance evaluations, it will be advantageous if the plastics model can serve as the format to be adapted to paper along with the main paper-related characteristics, in which the vapor pressure of migrants plays an important role, as was found in almost all studies. For understanding the processes, models must be more complex. Toward wetting or fatty contact, more research is also needed. Overall, the published scienti fi c data and collective knowledge in this area, along with modern molecular dynamics science, form a promising solid basis for future work to fi ll the open data gaps and generate the needed knowledge, thus ending up with a migration model of broad applicability and general acceptance.

The authors declare that fi nancial support was received for the research, authorship, and/or publication of this article. The work was partly funded by Industrievereinigung Lebensmitteltechnologie und Verpackung, 85354 Freising (www.ivlv.org within IVLV project “ Migration from paper and board 2 ” ). Project can be found in project database https://www.ivlv.org/en/project/migration-from- paper-and-board-2/

Con fl ict of interest

The authors declare that the research was conducted in the absence of any commercial or fi nancial relationships that could be construed as a potential con fl ict of interest.

Publisher ’ s note

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Supplementary material

Author contributions

The Supplementary Material for this article can be found online at: https://www.frontiersin.org/articles/10.3389/fchem.2024.1397913/ full#supplementary-material

AS: Conceptualization, funding acquisition, writing – original draft, and writing – review and editing. LH: Funding acquisition and writing – original draft. RF: Conceptualization and writing – original draft. References Aurela, B., and Ketoja, J. A. (2002). Diffusion of volatile compounds in fi bre networks: experiments and modelling by random walk simulation. Food Addit. Contam. 19, 56 – 62. doi:10.1080/02652030110083711 Aurela, B., Kulmala, H., and Soderhjelm, L. (1999). Phthalates in paper and board packaging and their migration into tenax and sugar. Food Addit. Contam. 16, 571 – 577. doi:10.1080/026520399283713 Baele, M., Vermeulen, A., Claes, M., Ragaert, P., and De Meulenaer, B. (2020). Migration of surrogate contaminants from paperboard to foods: effect of food and surrogate properties. Food Addit. Contam. Part A 37, 2165 – 2183. doi:10.1080/ 19440049.2020.1778184 Barnkob, L. L., and Petersen, J. H. (2013). Effect of relative humidity on the migration of benzophenone from paperboard into the food simulant Tenax ® and modelling hereof. Food Addit. Contam. Part A 30, 395 – 402. doi:10.1080/19440049. 2012.741717 Begley, T., Castle, L., Feigenbaum, A., Franz, R., Hinrichs, K., Lickly, T., et al. (2005). Evaluation of migration models that might be used in support of regulations for food-contact plastics. Food Addit. Contam. 22, 73 – 90. doi:10. 1080/02652030400028035 Begley, T. H., Hsu, W., Noonan, G., and Diachenko, G. (2008). Migration of fl uorochemical paper additives from food-contact paper into foods and food simulants. Food Addit. Contam. Part A 25, 384 – 390. doi:10.1080/ 02652030701513784 Beldi, G., Senaldi, C., Robouch, P., and Hoekstra, E. (2023). “ Testing conditions for kitchenware articles in contact with foodstuffs: plastics, metals, silicone and Rubber, paper and board - the EURL-FCM harmoised approach series, ” in JRC technical report (Luxembourg: Publicatons Of fi ce of the European Union). doi:10.2760/80698

SUPPLEMENTARY TABLE S1 Substances used in paper migration studies.

BfR (2015). “ Untersuchung der Stoffübergänge von Bedarfsgegenständen aus Papier, Karton und Pappe. Leitfaden des BfR vom 26, ” in Methodensammlung zur Untersuchung von Papier, Karton und Pappe für den Lebensmittelkontakt . BfR (2022a). “ 1 Allgemeine Methoden zur Untersuchung von Papier, Karton und Pappe 1.2 Herstellung eines Kaltwasserextraktes, ” in Methodensammlung zur Untersuchung von Papier, Karton und Pappe für den Lebensmittelkontakt . BfR (2022b). “ 1. Allgemeine Methoden zur Untersuchung von Papier, Karton und Pappe. 1.3 Herstellung eines Heißwasserextraktes, ” in Methodensammlung zur Untersuchung von Papier, Karton und Pappe für den Lebensmittelkontakt . Biedermann, M., and Grob, K. (2010). Is recycled newspaper suitable for food contact materials? Technical grade mineral oils from printing inks. Eur. Food Res. Technol. 230, 785 – 796. doi:10.1007/s00217-010-1223-9 Biedermann, M., and Grob, K. (2012). On-line coupled high performance liquid chromatography – gas chromatography for the analysis of contamination by mineral oil Part 2: migration from paperboard into dry foods: interpretation of chromatograms. J. Chromatogr. A 1255, 76 – 99. doi:10.1016/j.chroma.2012. 05.096 Biedermann, M., and Grob, K. (2013). Assurance of safety of recycled paperboard for food packaging through comprehensive analysis of potential migrants is unrealistic. J. Chromatogr. A 1293, 107 – 119. doi:10.1016/j.chroma.2013.04.009 Biedermann, M., Ingenhoff, J.-E., Dima, G., Zur fl uh, M., Biedermann-Brem, S., Richter, L., et al. (2013a). Migration of mineral oil from printed paperboard into dry foods: survey of the German market Part II: advancement of migration during storage. Eur. Food Res. Technol. 236, 459 – 472. doi:10.1007/s00217-012- 1909-2

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