PAPERmaking! Vol9 Nr1 2023

PAPER making! FROM THE PUBLISHERS OF PAPER TECHNOLOGY INTERNATIONAL ® FROM THE PUBLISHERS OF PAPER TE Volume 9, Number 1, 2023   

Kaolin-Filled Styrene-Butadiene-Based Dispersion Coatings for Paper-Based Packaging: Effect on Water, Moisture, and Grease Barrier Properties ANDREA MARINELLI 1,2 , MARIA VITTORIA DIAMANTI 1,2 , MARIAPIA PEDEFERRI 1,2 & BARBARA DEL CURTO 1,2 Dispersion coating may represent an alternative technology to extrusion coating, currently dominating the market of coated paper-based packaging. Being processed as inks, dispersion coatings can be applied with conventional equipment, achieving lower dry coat grammages. In this work, two styrene-butadiene-based (T g1 ≈ 0°C; T g2 ≈ 15°C) dispersion coatings filled with different amounts of kaolin were developed and rod- coated on two different paper substrates. The samples were tested for water, moisture, and grease barrier properties. Kaolin-containing formulations showed moisture barrier as low as 15 g/(m 2 .day), as well as grease barrier higher than 24 h. The best formulation involved 20% by weight of kaolin, whereas higher amounts were detrimental for water barrier, beneficial for moisture barrier, and slightly detrimental for grease barrier properties. Benchmarked to two commercial grades, kaolin-filled coatings strongly improved grease barrier, yet achieving similar moisture barrier. Contact information: 1 Department of Chemistry, Materials and Chemical Engineering “Giulio Natta”, Politecnico di Milano, Piazza Leonardo Da Vinci 32, 20133 Milan, Italy 2 National Interuniversity Consortium of Materials Science and Technology (INSTM), Via Giuseppe Giusti 9, 50121 Firenze, Italy

Coatings 2023, 13, 195. https://doi.org/10.3390/coatings13010195 Creative Commons Attribution 4.0 International License

The Paper Industry Technical Association (PITA) is an independent organisation which operates for the general benefit of its members – both individual and corporate – dedicated to promoting and improving the technical and scientific knowledge of those working in the UK pulp and paper industry. Formed in 1960, it serves the Industry, both manufacturers and suppliers, by providing a forum for members to meet and network; it organises visits, conferences and training seminars that cover all aspects of papermaking science. It also publishes the prestigious journal Paper Technology International ® and the PITA Annual Review , both sent free to members, and a range of other technical publications which include conference proceedings and the acclaimed Essential Guide to Aqueous Coating .

Article 4 – Coated Paper 



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