PAPER making! FROM THE PUBLISHERS OF PAPER TECHNOLOGY INTERNATIONAL Volume 6, Number 1, 2020
Cationic polyacrylamide induced flocculation and turbulent dewatering of microalgae on a Britt Dynamic Drainage Jar, Mutah Musa et al, Separation and Purification Technology, Vol.233 . Dewatering is one of the major constraints to the large scale production of microalgae biofuels, with many drawbacks in currently deployed technologies. Using an approach similar to papermaking, cationic polyacrylamide (CPAM) based flocculants can stabilize flocs of microalgae under turbulent conditions to achieve effective dewatering of dilute suspensions in high speed filtration systems. The effects of flocculant dosage, stirrer speed (i.e. turbulence) and pH on filtration retention was investigated using a Britt Dynamic Drainage Jar (BDDJ) which simulates a commercial paper machine. The development of a stable floc system that withstood turbulence was achieved through the flocculant’s dual effects of charge neutralization and bridging of the microalgae cells. Retention of microalgae on a 76 μm screen improved from 7% when no flocculant was used to 94 % at a flocculant dosage of 10 mg/L of CPAM, stirrer speed of 1200 rpm and pH of 6.5 as optimum conditions. The most significant effects on microalgae retention were that of flocculant dosage; followed by the combined interaction between stirrer speed and flocculant dosage; and that of pH. A key finding is that high retention was obtained under moderately turbulent conditions. This study shows that the paper dewatering technique will be potentially applicable for microalgae preconcentration in the production of biofuels, and further pilot scale studies are recommended. TISSUE A semi Ǧ quantitative job exposure matrix for dust exposures in Swedish soft tissue paper mills, Richard L. Neitzel et al, American Journal of Industrial Medicine, Vol.63(4) . Total paper dust exposure has been associated with respiratory problems among workers in the soft tissue paper industry. However, a comprehensive job exposure matrix (JEM) has not been developed for application to this industry. Our study was intended to address this need and to support further studies of mortality and morbidity in a cohort of Swedish workers from this industry. Synthesis and Application of a Cationic Polyamine as Yankee Dryer Coating Agent for the Tissue Paper-Making Process, Cesar Valencia et al, Polymers, Vol.12(1) . Tissue paper is of high importance worldwide and, continuously, research is focused on improvements of the softening and durability properties of the paper which depend specifically on the production process. Polyamide-amine-epichlorohydrin (PAE) resins along with release agents are widely used to adhere the paper to the yankee dryer (creping cylinder) in paper manufacture. Nevertheless, these resins are highly cationic and they normally adhere in excess to the paper which negatively affects the creping process and the quality of the paper. For this reason, a low cationic polyamine-epichlorohydrin coating (Polycoat 38®) was synthesized from a diamine supplied by Disproquin S.A.S. and epichlorohydrin. The analysis of the synthesized polymer was carried out by Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (1H-NMR). The molecular weight of the polymer was obtained by gel permeation chromatography (GPC), physical-chemical properties such as kinematic viscosity, percentage of solids, density, charge density were measured and compared with a commercial PAE resin (Dispro620®) Thermal stability of the Polycoat 38® and glass transition temperature in presence of a release agent (Disprosol 17®) were also evaluated by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC), respectively. Finally, a peel adhesion test and an absorption durability assessment were carried out together with the evaluation of the creeping efficiency of the paper by caliber and tensile measurements in a tissue (towel paper) production plant, demonstrating a superior performance in the paper creping process as compared to some commercially available products.
Technical Abstracts
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