PAPERmaking! Vol5 Nr1 2019

 PAPERmaking! FROM THE PUBLISHERS OF PAPER TECHNOLOGY  Volume 5, Number 1, 2019   Application of

soda-AQ to agricultural waste (okra stalks) from Sudan Safaa Hassan Omer 1 , Tarig Osman Khider 2 * , Osman Taha Elzaki 3 , Salaheldin Dafalla Mohieldin 3 and Suhair Kamal Shomeina 3 . pulping Abelmoschus esculentus okra as whole stalks was examined for its suitability for pulp and paper production. It’s, fiber dimensions, morphological and chemical characteristics were reported. The pulping trials with soda- Anthraquinone (AQ,) at different chemical charges. Application of 21% as NaOH with 0.1% AQ gave good results in degree of delignification, mechanical properties. Utilization of okra pulps and blender is recommended due to good pulp properties. Evaluation of general characteristics of okra stalks in terms of fiber dimensions morphological indices, chemical components, Soda-AQ cooking and to study their suitability for paper production. Okra Fiber dimension evaluation done after maceration with a mixture of 30% hydrogen peroxide and acetic acid (1:1) for core and bark parts separately and was carried out under microscope staining with aqueous safranin. The Soda-AQ cooks at different active alkali levels were calculated as NaOH on oven dry raw material. The fibers from okra stalks studied (core and bark) were in the range of hardwood fibers, with short fiber length, especially the core with more or less moderate walls, narrow lumen and fiber width. The fiber width of bark was medium – narrow with medium wall thickness. The ash content was rather high whereas the silica content was comparatively high The hot water extractives from okra stalks was (4.1%), cold water (0.4) ethanol/ cyclohexane (1.1), ethanol extractives (1.2%) and 1% NaOH (27.6%) were rather high. The cellulose (Kurschner-Hoffer) was (48.5%) The lignin content was (15.3%) which was relatively moderate. The use of 0.1% AQ enhanced the delignification in the three trials applied. The screened yield increase with increase of chemical dose applied while the rejects decrease. When 21% NaOH was applied, the screened yield was 32.2% with negligible amount of rejects, however with lower alkali charge 18% the screened yield was decreased to 28% with very low rejects 1.5%. on the other hand rejects were increased to 7% when 15% NaOH was applied with very low screened yield 19%.The pulps produced from okra soda-AQ are suitable for production  of printing and writing papers and it is advisable to use them in blending due to good papermaking properties. Contact information: 1 University of Bahri, College of Natural Resources and Environmental Studies, Khartoum, Sudan. 2 Industries Department, College of Applied and Industrial Sciences, University of Bahri Sudan, P.O. Box 1606, Khartoum, Sudan. 3 Cellulose Chemistry and Technology Research Unit, National Centre of Research, Khartoum, Sudan. Omer et al. BMC Chemical Engineering (2019) 1:6 https://doi.org/10.1186/s42480-019-0005-9

The Paper Industry Technical Association (PITA) is an independent organisation which operates for the general benefit of its members – both individual and corporate – dedicated to promoting and improving the technical and scientific knowledge of those working in the UK pulp and paper industry. Formed in 1960, it serves the Industry, both manufacturers and suppliers, by providing a forum for members to meet and network; it organises visits, conferences and training seminars that cover all aspects of papermaking science. It also publishes the prestigious journal Paper Technology International and the PITA Annual Review , both sent free to members, and a range of other technical publications which include conference proceedings and the acclaimed Essential Guide to Aqueous Coating .

Article 7 – Agriwaste 



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