PAPERmaking! Vol4 Nr2 2018

Top Curr Chem (Z) (2018) 376:3 https://doi.org/10.1007/s41061-017-0182-z

REVIEW

Green and Sustainable Separation of Natural Products from Agro-Industrial Waste: Challenges, Potentialities, and Perspectives on Emerging Approaches Vânia G. Zuin 1,2 · Luize Z. Ramin 1

Received: 30 August 2017 / Accepted: 26 December 2017 / Published online: 17 January 2018 © The Author(s) 2018. This article is an open access publication

Abstract New generations of biorefinery combine innovative biomass waste resources from different origins, chemical extraction and/or synthesis of biomate- rials, biofuels, and bioenergy via green and sustainable processes. From the very beginning, identifying and evaluating all potentially high value-added chemicals that could be removed from available renewable feedstocks requires robust, efficient, selective, reproducible, and benign analytical approaches. With this in mind, green and sustainable separation of natural products from agro-industrial waste is clearly attractive considering both socio-environmental and economic aspects. In this paper, the concepts of green and sustainable separation of natural products will be dis- cussed, highlighting the main studies conducted on this topic over the last 10 years. The principal analytical techniques (such as solvent, microwave, ultrasound, and supercritical treatments), by-products (e.g., citrus, coffee, corn, and sugarcane waste) and target compounds (polyphenols, proteins, essential oils, etc.) will be pre- sented, including the emerging green and sustainable separation approaches towards bioeconomy and circular economy contexts. Keywords Green and sustainable extraction · Sustainable separation · Green analytical techniques · Biomass waste · Biorefinery · Bioeconomy and circular economy

Chapter 8 was originally published as Zuin, V. G. & Ramin, L. Z. Top Curr Chem (Z) (2018) 376: 3. https://doi.org/10.1007/s41061-017-0182-z.

* Vânia G. Zuin

vaniaz@ufscar.br; vania.zuin@york.ac.uk

1 Department of Chemistry, Federal University of São Carlos, Rod. Washington Luís, km 235, São Carlos 13565-905, Brazil 2 Green Chemistry Centre of Excellence, University of York, North Yorkshire YO10 5DD, UK

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