PAPERmaking! FROM THE PUBLISHERS OF PAPER TECHNOLOGY Volume 5, Number 2, 2019
COATING Application of Some Polymer latexes in Preventing Paper Documents Forgery, Egyptian Journal of Chemistry , 62 (1), 2019, pp.1-14. The main objective of this research is to improve ink printability of papers via their modification with various types of water-based polymer latexes during paper manufacturing process. In order to achieve this target, various types of styrene-acrylate polymer latexes were used for modification of different types of papers. Styrene-acrylate latexes were prepared via emulsion polymerization of styrene with various acrylate monomers using emulsion polymerization technique. The effect of different emulsifying agents on the properties of the prepared emulsions was studied. The obtained results showed a significant improvement in degree of gloss and ink density on the polymer-coated papers which positively affect the ink ability, and ink holding properties of the modified paper. In addition, ink gloss and ink density of the coated papers improved with increasing the concentration of modifying latexes containing Texapon®P as emulsifier. These promising results open the way to use polymer latexes in treatment of documented value which can be used in stabilization of disappearing ink on paper leading to prevent forgery. Water vapour and grease resistance properties of paper coating based starch- bentonite clay Khairuddin et al, Journal of Physics: Conference Series , 1153, conference 1. In the present study, the water vapour and grease resistance properties of paper coating based starch – bentonite clay has been investigated. The clay concentration was 0%, 10%, 15%, 23%, 30%, 40% and 50% w/w. The composites were prepared by solution casting and coated on the surface of the paper, and analysed using Payne cup method (water vapour transmitter rate-WVTR), grease resistance test and X-Ray diffraction (XRD). The WVTR results showed that the addition of clay improved water vapour barrier properties and the most optimal improvement was obtained at clay concentration in the range of 10 - 23 wt %. However, the opposite trend was observed for grease resistance properties which showed that the grease resistance decreased with increasing clay concentration. XRD results showed that starch entered clay gallery and formed intercalated bilayer structure both at clay concentration of 10 and 23 wt % wt. The clay/starch composite (23 wt%) was more ordered and higher amount of starch chains entered gallery than than those of clay/starch (10 wt%) supporting better water barrier properties at high clay concentration. Effect of coating with novel bio nanocomposites of cationic starch/cellulose nanocrystals on the fundamental properties of the packaging paper, Khashayar Vaezi et al, Polymer Testing , 80, 2019, online. In this research, an environmentally friendly and biodegradable cationic starch (CS)/nanocrystalline cellulose (NCC) nanocomposite coating was produced and it was applied to improve the mechanical, barrier and physical properties of packaging kraft paper via surface coating. The mechanical and barrier properties of the paper were affected by the CS/NCC nanocomposite coating and it was the subject of investigation. CS/NCC nanocomposites were prepared by the solvent method. Structural and morphological properties of the nanocomposite were studied by FESEM and TEM observation. Results showed that the increased NCC nanoparticles loading, increased the tensile strength, oil resistance and air resistance of the coated paper. Also, the water absorption of the coated paper decreased 50% at 5 wt% NCC concentration. In our study it was concluded that the optimized amount for the NCC nanoparticles (among, 3 wt%, 5 wt%, and 7 wt%), is 5 wt%. The CS/NCC nanocomposite coatings are then proposed as a favorable booster which intensifies the mechanical and barrier properties of the paper in the food packaging application.
Technical Abstracts
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