Consumables Digital Catalogue

UHPLC/HPLC Columns

Shim-pack GIS HILIC

Ideal for the Separation of Highly Polar Basic Compounds Shim-pack GIS HILIC is designed for Hydrophilic Interaction Liquid Chromatography (HILIC). It is chemically bonded with a diol group, which provides excellent peak shape for basic and neutral polar compounds. Bonded Phase Particle Size Pore Size

Diol Groups 3 µm, 5 µm

10 nm

450 m 2 /g

Surface Area

Carbon Loading

20 %

In addition, HILIC is a variation of normal phase mode. It is capable of using organic solvents mixed with water as mobile phase, while normal phase mode uses non- aqueous organic solvents. In HILIC, the higher the organic concentration in the solvents, the greater is the retention of highly polar compounds.

End-capping

-

pH Range USP Code

2 to 7.5

L20

Analysis Examples

Peaks 1. Allantoin

Conditions

Column

: Shim-pack GIS HILIC (250 mmL. × 3.0 mmI.D., 5 µm) (P/N: 227-30639-07)

Mobile Phase : A) 10 mmol/L Ammonium acetate B) Acetonitrile A/B = 5/95 (v/v) Flow Rate : 0.4 mL/min Col. Temp. : 40 ºC Detection : UV 210 nm

Peaks (500 mg/L each) 1. Taurine 2. Inositol

Conditions

Column

: Shim-pack GIS HILIC (150 mmL. × 3.0 mmI.D., 5 µm) (P/N: 227-30639-06)

Mobile Phase : A) Water

B) Acetonitrile A/B = 20/80 (v/v)

Flow Rate Col. Temp. Detection

: 0.4 mL/min

: 40 ºC

: RID (35 ºC, positive)

Injection Vol. : 20 μL

Pg A-58

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