STYCCOBOND F46 According to UK REACH (S.I. 2019/758) Safety data sheet
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product identifier: STYCCOBOND F46 Other means of identification: Not relevant 1.2 Relevant identified uses of the substance or mixture and uses advised against: Relevant uses: Adhesive. For professional users only. Uses advised against: All uses not specified in this section or in section 7.3 1.3 Details of the supplier of the safety data sheet: F. Ball and Co. Ltd. Churnetside Business Park, Station Road ST13 7RS Cheddleton - Leek - England Phone: +44(0) 1538 361633 msds@f-ball.co.uk www.f-ball.com 1.4 Emergency telephone number: +44 (0) 1538 361633 Mon-Fri 08:30 - 17:00 (exc Bank Holidays)
SECTION 2: HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture:
GB CLP Regulation (UK S.I. 2019/720 and UK S.I. 2020/1567): The product is not classified as hazardous according to GB CLP Regulation (UK S.I. 2019/720 and UK S.I. 2020/1567). 2.2 Label elements: GB CLP Regulation (UK S.I. 2019/720 and UK S.I. 2020/1567): Hazard statements: Not relevant Precautionary statements: Not relevant Supplementary information: EUH208: Contains 1,2-benzisothiazol-3(2H)-one, Reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H- isothiazol-3-one (3:1). May produce an allergic reaction. EUH210: Safety data sheet available on request. 2.3 Other hazards: Product does not meet PBT/vPvB criteria
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Substance: Non-applicable 3.2 Mixture: Chemical description: Mixture of polymers, dispersants and organic compounds Components: In accordance with Annex II of The REACH etc. (Amendment etc.) (EU Exit) Regulations 2020, the product contains: Identification Chemical name/Classification
Concentration
Reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one (3:1) Acute Tox. 2: H310+H330; Acute Tox. 3: H301; Aquatic Acute 1: H400; Aquatic Chronic 1: H410; Eye Dam. 1: H318; Skin Corr. 1C: H314; Skin Sens. 1A: H317; EUH071 - Danger
<1 %
CAS: 55965-84-9
To obtain more information on the hazards of the substances consult sections 11, 12 and 16. Acute toxicity estimate for the substance in Part 3 of Annex VI to Regulation (EC) No 1272/2008 or as determined in accordance with Annex I to that Regulation:
- CONTINUED ON NEXT PAGE -
Page 1/9
Date of compilation: 14/03/2023
Revised: 06/06/2023
Version: 19 (Replaced 18)
STYCCOBOND F46 According to UK REACH (S.I. 2019/758) Safety data sheet
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS (continued)
Identification
Acute toxicity
Genus
Reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one (3:1)
LD50 oral
64 mg/kg
Rat
LD50 dermal
87.12 mg/kg Not relevant
Rabbit
CAS: 55965-84-9
LC50 inhalation
SECTION 4: FIRST AID MEASURES 4.1 Description of first aid measures: The symptoms resulting from intoxication can appear after exposure, therefore, in case of doubt, seek medical attention for direct exposure to the chemical product or persistent discomfort, showing the SDS of this product. By inhalation: This product is not classified as hazardous through inhalation. However, in case of intoxication symptoms it is recommended to remove the person affected from the area of exposure, provide clean air and keep at rest. Request medical attention if symptoms persist. By skin contact: This product is not classified as hazardous when in contact with the skin. However, in case of skin contact it is recommended to remove contaminated clothes and shoes, rinse the skin or if necessary shower the affected person thoroughly with cold water and neutral soap. In case of serious reaction consult a doctor. By eye contact: Rinse eyes thoroughly with water for at least 15 minutes. If the injured person uses contact lenses, these should be removed unless they are stuck to the eyes, in which case removal could cause further damage. In all cases, after cleaning, a doctor should be consulted as quickly as possible with the SDS for the product. By ingestion/aspiration: Do not induce vomiting, but if it does happen keep the head down to avoid aspiration. Keep the person affected at rest. Rinse
out the mouth and throat, as they may have been affected during ingestion. 4.2 Most important symptoms and effects, both acute and delayed: Acute and delayed effects are indicated in sections 2 and 11. 4.3 Indication of any immediate medical attention and special treatment needed: Not relevant
SECTION 5: FIREFIGHTING MEASURES 5.1 Extinguishing media: Suitable extinguishing media:
Product is non-flammable under normal conditions of storage, handling and use. In the case of combustion as a result of improper handling, storage or use preferably use polyvalent powder extinguishers (ABC powder), in accordance with the Regulation on fire protection systems. Unsuitable extinguishing media: Non-applicable 5.2 Special hazards arising from the substance or mixture: As a result of combustion or thermal decomposition reactive sub-products are created that can become highly toxic and, consequently, can present a serious health risk. 5.3 Advice for firefighters: Depending on the magnitude of the fire it may be necessary to use full protective clothing and self-contained breathing apparatus (SCBA). Minimum emergency facilities and equipment should be available (fire blankets, portable first aid kit,...). Additional provisions: Act in accordance with the Internal Emergency Plan and the Information Sheets on actions to take after an accident or other emergencies. Eliminate all sources of ignition. In case of fire, cool the storage containers and tanks for products susceptible to combustion, explosion or BLEVE as a result of high temperatures. Avoid spillage of the products used to extinguish the fire into an aqueous medium.
SECTION 6: ACCIDENTAL RELEASE MEASURES
- CONTINUED ON NEXT PAGE -
Page 2/9
Date of compilation: 14/03/2023
Revised: 06/06/2023
Version: 19 (Replaced 18)
STYCCOBOND F46 According to UK REACH (S.I. 2019/758) Safety data sheet
SECTION 6: ACCIDENTAL RELEASE MEASURES (continued) 6.1 Personal precautions, protective equipment and emergency procedures: For non-emergency personnel:
Isolate leaks provided that there is no additional risk for the people performing this task. Personal protection equipment must be used against potential contact with the spilt product (See section 8). Evacuate the area and keep out those who do not have protection. For emergency responders: Wear protective equipment. Keep unprotected persons away. See section 8. 6.2 Environmental precautions: It is recommended to avoid environmental spillage of both the product and its container. 6.3 Methods and material for containment and cleaning up: It is recommended: Absorb the spillage using sand or inert absorbent and move it to a safe place. Do not absorb in sawdust or other combustible absorbents. For any concern related to disposal consult section 13. 6.4 Reference to other sections: See sections 8 and 13. SECTION 7: HANDLING AND STORAGE 7.1 Precautions for safe handling: A.- General precautions for safe use Comply with the current legislation concerning the prevention of industrial risks with regards manually handling weights. Product is non-flammable under normal conditions of storage, handling and use. It is recommended to transfer at slow speeds to avoid the generation of electrostatic charges that can affect flammable products. Consult section 10 for information on conditions and materials that should be avoided. C.- Technical recommendations on general occupational hygiene Do not eat or drink during the process, washing hands afterwards with suitable cleaning products. D.-Technical recommendations to prevent environmental risks It is recommended to have absorbent material available at close proximity to the product (See subsection 6.3) 7.2 Conditions for safe storage, including any incompatibilities: A.- Specific storage requirements Minimum Temp.: 5 ºC Maximum Temp.: 30 ºC B.- General conditions for storage Avoid sources of heat, radiation, static electricity and contact with food. For additional information see subsection 10.5 7.3 Specific end use(s): Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this product. Maintain order, cleanliness and dispose of using safe methods (section 6). B.- Technical recommendations for the prevention of fires and explosions
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters: Substances whose occupational exposure limits have to be monitored in the workplace: There are no applicable occupational exposure limits for the substances contained in the product DNEL (Workers): Not relevant DNEL (General population): Not relevant - CONTINUED ON NEXT PAGE - Date of compilation: 14/03/2023 Revised: 06/06/2023 Version: 19 (Replaced 18)
Page 3/9
STYCCOBOND F46 According to UK REACH (S.I. 2019/758) Safety data sheet
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continued) PNEC: Not relevant 8.2 Exposure controls: A.- Individual protection measures, such as personal protective equipment
As a preventative measure it is recommended to use basic Personal Protective Equipment, with the corresponding <<UKCA marking>> or <<CE marking>>. For more information on Personal Protective Equipment (storage, use, cleaning, maintenance, class of protection,…) consult the information leaflet provided by the manufacturer. For more information see subsection 7.1. All information contained herein is a recommendation which needs some specification from the labour risk prevention services as it is not known whether the company has additional measures at its disposal. B.- Respiratory protection The use of protection equipment will be necessary if a mist forms or if the occupational exposure limits are exceeded. C.- Specific protection for the hands Pictogram PPE Remarks Replace gloves in case of any sign of damage. For prolonged periods of exposure to the product for professional users/industrials, we recommend using CE III gloves in line with standards EN ISO 21420:2020 and EN ISO 374-1:2016+ A1:2018 As the product is a mixture of several substances, the resistance of the glove material can not be calculated in advance with total reliability and has therefore to be checked prior to the application. D.-Eye and face protection Pictogram PPE Remarks Mandatory hand protection Protective gloves against minor risks
Clean daily and disinfect periodically according to the manufacturer´s instructions. Use if there is a risk of splashing.
Panoramic glasses against splash/projections.
Mandatory face protection
E.- Body protection Pictogram
PPE
Remarks
Replace before any evidence of deterioration. For periods of prolonged exposure to the product for professional/industrial users CE III is recommended, in accordance with the regulations in EN ISO 6529:2013, EN ISO 6530:2005, EN ISO 13688:2013, EN 464:1994.
Work clothing
Replace before any evidence of deterioration. For periods of prolonged exposure to the product for professional/industrial users CE III is recommended, in accordance with the regulations in EN ISO 20345:2012 y EN 13832-1:2007
Anti-slip work shoes
F.- Additional emergency measures Emergency measure
Standards
Emergency measure
Standards
ANSI Z358-1 ISO 3864-1:2011, ISO 3864-4:2011
DIN 12 899 ISO 3864-1:2011, ISO 3864-4:2011
Emergency shower
Eyewash stations
Environmental exposure controls: In accordance with the community legislation for the protection of the environment it is recommended to avoid environmental spillage of both the product and its container. For additional information see subsection 7.1.D The Volatile Organic Compounds in Paints, Varnishes and Vehicle Refinishing Products Regulations 2012: V.O.C. (Supply): 0 % weight V.O.C. density at 20 ºC: 0 kg/m³ (0 g/L)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES *Not relevant due to the nature of the product, not providing information property of its hazards.
- CONTINUED ON NEXT PAGE -
Page 4/9
Date of compilation: 14/03/2023
Revised: 06/06/2023
Version: 19 (Replaced 18)
STYCCOBOND F46 According to UK REACH (S.I. 2019/758) Safety data sheet
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (continued) 9.1 Information on basic physical and chemical properties: For complete information see the product datasheet. Appearance: Physical state at 20 ºC: Liquid Appearance: Viscous Colour: White Odour: Not available Odour threshold: Not relevant * Volatility: Boiling point at atmospheric pressure: Not relevant * Vapour pressure at 20 ºC: Not relevant * Vapour pressure at 50 ºC:
<300000 Pa (300 kPa)
Evaporation rate at 20 ºC: Product description: Density at 20 ºC: Relative density at 20 ºC: Dynamic viscosity at 20 ºC: Kinematic viscosity at 20 ºC: Kinematic viscosity at 40 ºC:
Not relevant *
Not relevant *
1
30000 - 50000 cP Not relevant * >20.5 mm²/s Not relevant *
Concentration:
pH:
4 - 6
Vapour density at 20 ºC:
Not relevant * Not relevant * Not relevant * Not relevant * Not relevant * Not relevant *
Partition coefficient n-octanol/water 20 ºC:
Solubility in water at 20 ºC:
Solubility properties:
Decomposition temperature: Melting point/freezing point:
Flammability: Flash Point:
Non Flammable (>60 ºC)
Flammability (solid, gas): Autoignition temperature: Lower flammability limit: Upper flammability limit: Particle characteristics: Median equivalent diameter:
Not relevant * Not relevant * Not relevant * Not relevant *
Non-applicable
9.2 Other information:
Information with regard to physical hazard classes: Explosive properties:
Not relevant * Not relevant * Not relevant * Not relevant * Not relevant *
Oxidising properties: Corrosive to metals: Heat of combustion:
Aerosols-total percentage (by mass) of flammable components:
Other safety characteristics: Surface tension at 20 ºC:
Not relevant * *Not relevant due to the nature of the product, not providing information property of its hazards.
- CONTINUED ON NEXT PAGE -
Page 5/9
Date of compilation: 14/03/2023
Revised: 06/06/2023
Version: 19 (Replaced 18)
STYCCOBOND F46 According to UK REACH (S.I. 2019/758) Safety data sheet
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (continued) Refraction index: Not relevant * *Not relevant due to the nature of the product, not providing information property of its hazards.
SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity: No hazardous reactions are expected because the product is stable under recommended storage conditions. See section 7 from Safety Data Sheet. 10.2 Chemical stability: Chemically stable under the indicated conditions of storage, handling and use. 10.3 Possibility of hazardous reactions: Under the specified conditions, hazardous reactions that lead to excessive temperatures or pressure are not expected. 10.4 Conditions to avoid: Applicable for handling and storage at room temperature: Shock and friction Contact with air Increase in temperature Sunlight Humidity Not applicable Not applicable Not applicable Not applicable Not applicable 10.5 Incompatible materials: Acids Water Oxidising materials Combustible materials Others Avoid strong acids Not applicable Avoid direct impact Not applicable Avoid alkalis or strong bases 10.6 Hazardous decomposition products: See subsection 10.3, 10.4 and 10.5 to find out the specific decomposition products. Depending on the decomposition conditions, complex mixtures of chemical substances can be released: carbon dioxide (CO₂), carbon monoxide and other organic compounds. SECTION 11: TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects: The experimental information related to the toxicological properties of the product itself is not available Dangerous health implications: In case of exposure that is repetitive, prolonged or at concentrations higher than the recommended occupational exposure limits, adverse effects on health may result, depending on the means of exposure: A- Ingestion (acute effect): - Acute toxicity: Based on available data, the classification criteria are not met, however, it contains substances classified as dangerous for consumption. For more information see section 3. - Corrosivity/Irritability: Based on available data, the classification criteria are not met. However, it does contain substances classified as hazardous for this effect. For more information see section 3. B- Inhalation (acute effect): - Acute toxicity : Based on available data, the classification criteria are not met. However, it contains substances classified as hazardous for inhalation. For more information see section 3. - Corrosivity/Irritability: Prolonged inhalation of the product is corrosive to mucous membranes and the upper respiratory tract C- Contact with the skin and the eyes (acute effect): - Contact with the skin: Based on available data, the classification criteria are not met. However, it contains substances classified as hazardous for skin contact. For more information see section 3. - Contact with the eyes: Based on available data, the classification criteria are not met. However, it does contain substances
classified as hazardous for this effect. For more information see section 3. D- CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction):
- CONTINUED ON NEXT PAGE -
Page 6/9
Date of compilation: 14/03/2023
Revised: 06/06/2023
Version: 19 (Replaced 18)
STYCCOBOND F46 According to UK REACH (S.I. 2019/758) Safety data sheet
SECTION 11: TOXICOLOGICAL INFORMATION (continued) - Carcinogenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as hazardous for the effects mentioned. For more information see section 3. IARC: Not relevant - Mutagenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as hazardous for this effect. For more information see section 3. - Reproductive toxicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as hazardous for this effect. For more information see section 3. E- Sensitizing effects: - Respiratory: Based on available data, the classification criteria are not met, as it does not contain substances classified as hazardous with sensitising effects. For more information see section 3. - Skin: Based on available data, the classification criteria are not met. However, it contains substances classified as dangerous with sensitising effects. For more information see section 3. F- Specific target organ toxicity (STOT) - single exposure: Based on available data, the classification criteria are not met, as it does not contain substances classified as hazardous for this effect. For more information see section 3. G- Specific target organ toxicity (STOT)-repeated exposure: - Specific target organ toxicity (STOT)-repeated exposure: Based on available data, the classification criteria are not met, as it does not contain substances classified as hazardous for this effect. For more information see section 3. - Skin: Based on available data, the classification criteria are not met, as it does not contain substances classified as hazardous for this effect. For more information see section 3. H- Aspiration hazard: Based on available data, the classification criteria are not met, as it does not contain substances classified as hazardous for this effect. For more information see section 3. Other information: Not relevant Specific toxicology information on the substances: Identification Acute toxicity Genus Reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one (3:1) LD50 oral 64 mg/kg Rat CAS: 55965-84-9 LD50 dermal 87.12 mg/kg Rabbit LC50 inhalation 0.33 mg/L (4 h) Rat SECTION 12: ECOLOGICAL INFORMATION The experimental information related to the eco-toxicological properties of the product itself is not available Based on available data, the classification criteria are not met. However, it does contain substances classified as hazardous for this effect. For more information see section 3. 12.1 Toxicity: Acute toxicity: Identification Concentration Species Genus Reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one and 2- methyl-2H-isothiazol-3-one (3:1) LC50 >0.1 - 1 mg/L (96 h) Fish CAS: 55965-84-9 EC50 >0.1 - 1 mg/L (48 h) Crustacean EC50 >0.1 - 1 mg/L (72 h) Algae 12.2 Persistence and degradability: Not available 12.3 Bioaccumulative potential: Not available 12.4 Mobility in soil: Not available 12.5 Results of PBT and vPvB assessment: Product does not meet PBT/vPvB criteria
- CONTINUED ON NEXT PAGE -
Page 7/9
Date of compilation: 14/03/2023
Revised: 06/06/2023
Version: 19 (Replaced 18)
STYCCOBOND F46 According to UK REACH (S.I. 2019/758) Safety data sheet
SECTION 12: ECOLOGICAL INFORMATION (continued) 12.6 Other adverse effects: Not described
SECTION 13: DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods: Code
Description
Waste class
08 04 10 waste adhesives and sealants other than those mentioned in 08 04 09
Non-hazardous
Type of waste: Not relevant Waste management (disposal and evaluation):
Consult the authorized waste service manager on the assessment and disposal operations in accordance The Waste (England & Wales) Regulations 2011, 2011 No. 988. As under 15 01 of the code and in case the container has been in direct contact with the product, it will be processed the same way as the actual product. Otherwise, it will be processed as non-hazardous residue. Waste should not be disposed of to drains. See paragraph 6.2. Regulations related to waste management: In accordance with Annex II of UK REACH the provisions related to waste management are stated: UK legislation: The Waste (England & Wales) Regulations 2011.
SECTION 14: TRANSPORT INFORMATION
This product is not regulated for transport (ADR/RID,IMDG,IATA)
SECTION 15: REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture: - Substances listed in UK candidate list of substances of very high concern (SVHCs): Not relevant - Substances listed in UK REACH Authorisation List (Annex 14): Not relevant The Control of Major Accident Hazards Regulations 2015: Not relevant Restrictions to commercialisation and the use of certain dangerous substances and mixtures (Annex XVII UK REACH, etc ….): Not relevant Specific provisions in terms of protecting people or the environment: It is recommended to use the information included in this safety data sheet as a basis for conducting workplace-specific risk assessments in order to establish the necessary risk prevention measures for the handling, use, storage and disposal of this product. Other legislation: The REACH etc. (Amendment etc.) (EU Exit) Regulations 2020. The Chemicals (Health and Safety) and Genetically Modified Organisms (Contained Use) (Amendment etc.) (EU Exit) Regulations 2020. Control of Substances Hazardous to Health Regulations 2002 (as amended) EH40/2005 Workplace exposure limits.
SECTION 16: OTHER INFORMATION
Legislation related to safety data sheets: This safety data sheet has been designed in accordance with ANNEX II-The REACH etc. (Amendment etc.) (EU Exit) Regulations 2020. Texts of the legislative phrases mentioned in section 3: The phrases indicated do not refer to the product itself; they are present merely for informative purposes and refer to the individual components which appear in section 3
- CONTINUED ON NEXT PAGE -
Page 8/9
Date of compilation: 14/03/2023
Revised: 06/06/2023
Version: 19 (Replaced 18)
STYCCOBOND F46 According to UK REACH (S.I. 2019/758) Safety data sheet
SECTION 16: OTHER INFORMATION (continued) GB CLP Regulation (UK S.I. 2019/720 and UK S.I. 2020/1567): Acute Tox. 2: H310+H330 - Fatal in contact with skin or if inhaled. Acute Tox. 3: H301 - Toxic if swallowed. Aquatic Acute 1: H400 - Very toxic to aquatic life. Aquatic Chronic 1: H410 - Very toxic to aquatic life with long lasting effects. Eye Dam. 1: H318 - Causes serious eye damage. Skin Corr. 1C: H314 - Causes severe skin burns and eye damage. Skin Sens. 1A: H317 - May cause an allergic skin reaction. Classification procedure: Not relevant Advice related to training: Training is recommended in order to prevent industrial risks for staff using this product and to facilitate their comprehension and interpretation of this safety data sheet, as well as the label on the product. Principal bibliographical sources:
http://echa.europa.eu http://eur-lex.europa.eu Abbreviations and acronyms: ADR: European agreement concerning the international carriage of dangerous goods by road IMDG: International maritime dangerous goods code
IATA: International Air Transport Association ICAO: International Civil Aviation Organisation COD: Chemical Oxygen Demand BOD5: 5day biochemical oxygen demand BCF: Bioconcentration factor LD50: Lethal Dose 50 LogPOW: Octanolwater partition coefficient Koc: Partition coefficient of organic carbon UFI: unique formula identifier IARC: International Agency for Research on Cancer LC50: Lethal Concentration 50 EC50: Effective concentration 50
The information contained in this safety data sheet is based on sources, technical knowledge and current legislation at UK, without being able to guarantee its accuracy. This information cannot be considered a guarantee of the properties of the product, it is simply a description of the security requirements. The occupational methodology and conditions for users of this product are not within our awareness or control, and it is ultimately the responsibility of the user to take the necessary measures to obtain the legal requirements concerning the manipulation, storage, use and disposal of chemical products. The information on this safety data sheet only refers to this product, which should not be used for needs other than those specified. - END OF SAFETY DATA SHEET - Date of compilation: 14/03/2023 Revised: 06/06/2023 Version: 19 (Replaced 18) Page 9/9
Page 1 Page 2 Page 3 Page 4 Page 5 Page 6 Page 7 Page 8 Page 9Made with FlippingBook - Online catalogs