Tampa Brass Aluminum Corp – AS9100D Quality Management System
W/I No.:
WI_OAT_JK400Q
Title: JetKote 400 Q Refractory Coating – Work Instruction
Rev: 0
CHANGE HISTORY
FROM Rev:
TO Rev:
Date of Change
Short Description of Change
Change Made By:
0
0
01/27/2026
Initial Release
Engineering
Applies To: Mold & Core Preparation / Foundry Coating
Product: JetKote 400 Q (HA-International)
1. PURPOSE
Define the standardized process for receiving, inspecting, preparing, applying, verifying, curing, documenting, and re-applying JetKote 400 Q refractory coating to ensure compliance with Engineering requirements, Quality standards, safety controls, and AS9100 traceability expectations.
2. SCOPE
This Work Instruction applies to:
Receiving personnel
•
Operators performing mold/core coating
•
• Quality and Engineering personnel performing verification and approval
• Supervisors overseeing coating preparation and execution
This WI applies to all work orders and BOMs specifying JetKote 400 Q.
3. RESPONSIBILITIES
3.1 Engineering
• Approve JetKote 400 Q use on Work Orders and BOMs
• Specify application method, coating thickness, and cure requirements
• Approve any thinning, deviation, or re-application in writing
Provide final acceptance sign-off
•
Page 1 of 8
Tampa Brass Aluminum Corp – AS9100D Quality Management System
W/I No.:
WI_OAT_JK400Q
Title: JetKote 400 Q Refractory Coating – Work Instruction
Rev: 0
3.2 Quality
Verify material conformance upon receipt
•
• Verify coating thickness using calibrated gauges
• Reject nonconforming material or process execution
Maintain required quality records
•
3.3 Operators
Follow this WI exactly as written
•
• Stop work and notify Engineering or Quality if instructions are unclear
Complete all required documentation
•
3.4 Receiving
Perform incoming inspection per Section 5
•
• Prevent release of nonconforming material to production
4. REFERENCES
JetKote 400 Q Safety Data Sheet (SDS)
•
Approved Bill of Materials (BOM)
•
Work Order / Traveler
•
Engineering mold and core drawings
•
Calibrated coating thickness gauges
•
• AS9100D Quality Management System requirements
Page 2 of 8
Tampa Brass Aluminum Corp – AS9100D Quality Management System
W/I No.:
WI_OAT_JK400Q
Title: JetKote 400 Q Refractory Coating – Work Instruction
Rev: 0
5. MATERIAL RECEIVING & INSPECTION
5.1 Incoming Documentation Verification
Verify delivered material matches approved BOM and Work Order.
Confirm container label includes:
Product Name: JetKote 400 Q
•
• Manufacturer: HA-International (or approved supplier)
Batch / Lot Number
•
Confirm SDS and Certificate of Analysis (COA) are available.
Receiving Inspector Initials: __________ Date Received: __________ BOM / PO Reference: __________________
5.2 Physical Condition Inspection
Inspect each container for:
Dents, bulges, or damaged seals
•
Leakage, rust, or contamination
•
Clear and legible labeling
•
If ANY issue is found:
Quarantine material
•
Notify Quality
•
Document nonconformance
•
Reject material if:
Labeling is missing or illegible
•
Container integrity is compromised
•
Batch / Lot #: ___________________________
Page 3 of 8
Tampa Brass Aluminum Corp – AS9100D Quality Management System
W/I No.:
WI_OAT_JK400Q
Title: JetKote 400 Q Refractory Coating – Work Instruction
Rev: 0
6. MATERIAL IDENTIFICATION & TRACEABILITY
• Record batch/lot number on Work Order, traveler, and traceability logs
Cross-reference batch to SDS and COA
•
• Store coating in designated, labeled area per SDS
• Do NOT commingle batches unless Engineering approves in writing
7. PRE-APPLICATION PREPARATION
7.1 Mold / Core Surface Preparation
Verify all surfaces to be coated are:
Dry
•
Free of loose sand
•
Free of oil, moisture, or foreign material
•
Clean surfaces using:
Dry brush (refractory-rated)
•
Low-pressure compressed air (<30 psi)
•
Vacuum as required
•
Reject and re-clean any surface showing contamination.
7.2 Coating Preparation
Verify correct coating prior to use:
Confirm label reads JetKote 400 Q
•
Verify batch/lot matches Work Order
•
Confirm product is within shelf life
•
Container handling:
• Place container on stable surface in ventilated area
Open container slowly
•
Page 4 of 8
Tampa Brass Aluminum Corp – AS9100D Quality Management System
W/I No.:
WI_OAT_JK400Q
Title: JetKote 400 Q Refractory Coating – Work Instruction
Rev: 0
• Visually inspect for contamination or abnormal condition
Mixing / agitation:
Use clean, dedicated tools only
•
Mix thoroughly to uniform consistency
•
Avoid excessive air entrainment
•
Thinning:
• Do NOT thin unless Engineering approval is documented
• If approved, record solvent type, ratio, and authorization reference
Usage control:
Keep container covered when not in use
•
• Use coating within approved timeframe after opening
Pre-application verification:
• Confirm viscosity and flow suitable for selected method
• Verify ambient temperature and conditions are acceptable
8. APPLICATION METHOD VERIFICATION
Verify approved application method per Engineering:
☐ Spray ☐ Brush ☐ Swab ☐ Dip
Engineering Initials: __________________
Page 5 of 8
Tampa Brass Aluminum Corp – AS9100D Quality Management System
W/I No.:
WI_OAT_JK400Q
Title: JetKote 400 Q Refractory Coating – Work Instruction
Rev: 0
9. PERSONAL PROTECTIVE EQUIPMENT (PPE)
Verify operator is using appropriate PPE:
Chemical-resistant gloves
•
Safety goggles and/or face shield
•
• Protective clothing (long sleeves; flame-resistant recommended)
Respiratory protection when required
•
Hearing protection if applicable
•
Failure to use PPE requires immediate work stoppage.
10. COATING APPLICATION
10.1 Coating Locations
Apply coating only to Engineering-approved surfaces:
Cope: __________ Drag: __________ Core: __________
10.2 Application Quality
Verify coating is:
Even and uniform
•
Free of runs, sags, or bare areas
•
Not blocking vents, gates, or risers
•
Stop and correct if defects are observed.
11. QUALITY VERIFICATION
11.1 Coating Thickness Verification
Verify thickness using calibrated gauge per Engineering specification.
Target Thickness: __________________ Measured Thickness: __________________
If out of tolerance:
Page 6 of 8
Tampa Brass Aluminum Corp – AS9100D Quality Management System
W/I No.:
WI_OAT_JK400Q
Title: JetKote 400 Q Refractory Coating – Work Instruction
Rev: 0
Stop work
•
Document nonconformance
•
Proceed to re-application per Section 13
•
Inspector Initials: __________ Date / Time: __________
11.2 Visual Inspection
Verify:
Uniform coating coverage
•
Proper adhesion
•
No contamination
•
Proper edge coverage
•
Pass / Fail (circle one)
12. CURING
Cure coating per Engineering or manufacturer requirements.
Cure Start Time: __________ Cure Complete Time: __________
Do not proceed until curing is complete and approved.
13. NONCONFORMANCE & RE-APPLICATION
13.1 Conditions Requiring Re-Application
Thickness out of specification
•
Poor adhesion
•
Surface contamination
•
Damage during handling
•
13.2 Re-Application Procedure
Page 7 of 8
Tampa Brass Aluminum Corp – AS9100D Quality Management System
W/I No.:
WI_OAT_JK400Q
Title: JetKote 400 Q Refractory Coating – Work Instruction
Rev: 0
• Remove defective coating using approved method
Re-clean and re-prepare surface
•
Re-apply coating per this WI
•
Re-measure and re-inspect
•
Obtain Engineering re-approval
•
Corrective Description: ___________________________________________
Performed By: __________ Date: __________ Engineering Re-Approval: __________ Date: __________
14. RECORDS & DOCUMENT RETENTION
Maintain records for:
Receiving inspection
•
Batch/lot traceability
•
Thickness measurements
•
Visual inspections
•
Engineering approvals
•
Re-application actions
•
Gauge calibration
•
Records retained per Quality Management System requirements.
15. SAFETY & HANDLING NOTES
JetKote 400 Q is flammable
•
Keep away from ignition sources
•
Avoid breathing vapors
•
Follow SDS for spill cleanup and disposal
•
Dispose of containers per regulatory requirements
•
Page 8 of 8
SAFETY DATA SHEET
JetKote 400 Q
Version 2.0
Revision Date: 11/08/2022
SDS Number: V_0000019497
Date of last issue: - Date of first issue: 09/25/2020
SECTION 1. IDENTIFICATION
Product name
: JetKote 400 Q
Manufacturer or supplier's details Company name of supplier
: HA-International, LLC safetydatasheet@ha-group.com
Address
: 630 Oakmont Lane Westmont IL 60559
Telephone
: General Assistance: (630) 575-5700 EH&S: (630) 575-5705 Regulatory Affairs: (630) 575-5722 Customer Service: +1 (800) 323-6863
Website
: www.ha-international.com
Contact person
: Jacqueline Ramirez (630) 575-5722, Jeff Krause (630) 575- 5705
Emergency telephone num- ber
: Medical Emergency: +1(303) 389-1396 Toll Free: +1(866) 595-5738
Recommended use of the chemical and restrictions on use Recommended use
: Refractory coating for foundry applications
Restrictions on use
: For industrial use only.
SECTION 2. HAZARDS IDENTIFICATION
GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR 1910.1200) Flammable liquids : Category 2
Eye irritation
: Category 2A
Skin sensitisation
: Category 1
Carcinogenicity
: Category 1A
Specific target organ toxicity - single exposure
: Category 3 (Central nervous system)
GHS label elements Hazard pictograms
:
Signal word
: Danger
Hazard statements
: Highly flammable liquid and vapour., May cause an allergic skin reaction., Causes serious eye irritation., May cause drowsiness or dizziness., May cause cancer.
1 / 22
SAFETY DATA SHEET
JetKote 400 Q
Version 2.0
Revision Date: 11/08/2022
SDS Number: V_0000019497
Date of last issue: - Date of first issue: 09/25/2020
Precautionary statements
:
Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equip- ment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust, vapors or spray. Wash skin thoroughly after handling. Use only outdoors or in a well-ventilated area. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves and eye protection. Response: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel un- well. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical attention. If skin irritation or rash occurs: Get medical attention if symp- toms persist. If eye irritation persists: Get medical attention. Wash contaminated clothing before reuse. In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. Storage: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up. Disposal: Dispose of contents and container to an approved waste dis- posal plant.
Other hazards Spray application of refractory coatings can result in inhalation exposure to the coating compo- nents, including crystalline silica (quartz), zircon, and solvent vapors, unless effective controls are employed. Refractory coatings may contain crystalline silica in a finely divided state. Dry product residues can potentially yield hazardous airborne concentrations if disturbed. This product contains trace amounts of the Naturally Occurring Radioactive Materials (NORMs) uranium and thorium. Chronic inhalation exposure to uranium and thorium may cause lung can- cer.
2 / 22
SAFETY DATA SHEET
JetKote 400 Q
Version 2.0
Revision Date: 11/08/2022
SDS Number: V_0000019497
Date of last issue: - Date of first issue: 09/25/2020
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Components Chemical name
CAS-No.
Concentration (% w/w)
Zircon
14940-68-2
>= 65 - < 70 >= 20 - < 25 >= 0.1 - < 1 >= 0.1 - < 1 >= 0.1 - < 1
Isopropyl alcohol
67-63-0
Rosin
8050-09-7 14808-60-7 13463-67-7
Quartz (SiO2) Titanium dioxide
Actual concentration is withheld as a trade secret Significant Trace Elements Contained in the Crystalline Structure of Zircon: Uranium & Thorium 4.1 - 4.6 Bq/g (109.9 - 124.3 pCi/g) Radium (226) 3.48 - 4.29 Bq/g (94-116 pCi/g) Hafnium (174) 0.038 Bq/g (1.03 pCi/g) Radium (228) 0.48 - 0.59 Bq/g (13-16 pCi/g). Other decay products: in secular equilibrium.
SECTION 4. FIRST AID MEASURES
General advice
: Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. : Remove person to fresh air. If signs/symptoms continue, get medical attention. Oxygen or artificial respiration if needed. Consult a physician after significant exposure. If unconscious, place in recovery position and seek medical advice.
If inhaled
In case of skin contact
: If on skin, rinse well with water. If on clothes, remove clothes.
In case of eye contact
: Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist.
If swallowed
: Keep respiratory tract clear. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician. Take victim immediately to hospital. : May cause an allergic skin reaction. Causes serious eye irritation. May cause drowsiness or dizziness. May cause cancer.
Most important symptoms and effects, both acute and delayed
Notes to physician
: Treat symptomatically.
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media : High volume water jet
3 / 22
SAFETY DATA SHEET
JetKote 400 Q
Version 2.0
Revision Date: 11/08/2022
SDS Number: V_0000019497
Date of last issue: - Date of first issue: 09/25/2020
Specific hazards during fire- fighting
: Do not allow run-off from fire fighting to enter drains or water courses.
Hazardous combustion prod- ucts
: Smoke, carbon monoxide, and other products of incomplete combustion.
Further information
: Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. For safety reasons in case of fire, cans should be stored sepa- rately in closed containments. Use a water spray to cool fully closed containers. : Wear self-contained breathing apparatus for firefighting if nec- essary.
Special protective equipment for firefighters
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protec- tive equipment and emer- gency procedures
: Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentra- tions. Vapours can accumulate in low areas. : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. : Contain spillage, and then collect with non-combustible ab- sorbent material, (e.g. sand, earth, diatomaceous earth, ver- miculite) and place in container for disposal according to local / national regulations (see section 13).
Environmental precautions
Methods and materials for containment and cleaning up
SECTION 7. HANDLING AND STORAGE
Technical measures
: Storage and handling operations should be in conformance with OSHA 1910.106; Flammable Liquids; and the locally ap- plicable fire code. Spray application operations should be in conformance with NFPA 33; Standard for Spray Application of Flammable or Combustible Materials, Latest Edition Handling areas should be in conformance with NFPA 497; Recommended Practice for the Classification of Flammable Liquids, Gasses, or Vapors and of Hazardous (Classified) Locations for Electrical Installations in Chemical Process Are- as, Latest Edition, and other applicable standards related to control of ignition sources. Fast closing lids actuated by a fusible link device have proven effective in managing risks associated with a pool fire in dip tanks, flow-coat holding vessels, and similar open vessels containing flammable coatings. Spray application of refractory coatings can result in inhalation
4 / 22
SAFETY DATA SHEET
JetKote 400 Q
Version 2.0
Revision Date: 11/08/2022
SDS Number: V_0000019497
Date of last issue: - Date of first issue: 09/25/2020
exposure to the coating components, including crystalline silica (quartz), zircon, and solvent vapors, unless effective controls are employed. Overspray containment and exhaust systems (i.e., spray paint booths) are recommended for re- fractory coating spray applications. : Do not spray on a naked flame or any incandescent material. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Use only explosion-proof equipment. Keep away from open flames, hot surfaces and sources of ignition. : Avoid formation of aerosol. Do not breathe vapours/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the ap- plication area. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms. Open drum carefully as content may be under pressure. Dispose of rinse water in accordance with local and national regulations. Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. : Store in accordance with local fire code requirements. Prohibit smoking, hot work, and other ignition sources in prod- uct storage areas. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. : No decomposition if stored and applied as directed.
Advice on protection against fire and explosion
Advice on safe handling
Conditions for safe storage
Further information on stor- age stability
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters Components CAS-No.
Value type (Form of exposure)
Control parame- ters / Permissible concentration
Basis
Zircon
14940-68-2
TWA
5 mg/m3 (Zirconium) 5 mg/m3 (Zirconium) 10 mg/m3 (Zirconium) 5 mg/m3 (Zirconium) 10 mg/m3
OSHA Z-1
TWA
ACGIH
STEL
ACGIH
TWA
NIOSH REL
ST
NIOSH REL
5 / 22
SAFETY DATA SHEET
JetKote 400 Q
Version 2.0
Revision Date: 11/08/2022
SDS Number: V_0000019497
Date of last issue: - Date of first issue: 09/25/2020
(Zirconium)
Isopropyl alcohol
67-63-0
TWA STEL
200 ppm 400 ppm
ACGIH ACGIH
ST
500 ppm 1,225 mg/m3 400 ppm 980 mg/m3 400 ppm 980 mg/m3 0.05 mg/m3 10 mg/m3 / %SiO2+2 250 mppcf / %SiO2+5 0.025 mg/m3 (Silica)
NIOSH REL
TWA
NIOSH REL
TWA
OSHA Z-1
Quartz (SiO2)
14808-60-7
TWA (Res- pirable dust) TWA (respir- able) TWA (respir- able) TWA (Res- pirable par- ticulate mat- ter) PEL (respir- able) TWA (Res- pirable dust) TWA (total dust)
OSHA Z-1
OSHA Z-3
OSHA Z-3
ACGIH
0.05 mg/m3
OSHA CARC
0.05 mg/m3 (Silica) 15 mg/m3
NIOSH REL
Titanium dioxide
13463-67-7
OSHA Z-1
TWA
10 mg/m3 (Titanium dioxide)
ACGIH
Biological occupational exposure limits Components CAS-No. Control parameters
Biological specimen
Sam- pling time
Permissible concentra- tion
Basis
Isopropyl alcohol
67-63-0
Acetone
Urine
End of shift at end of
40 mg/l
ACGIH BEI
work- week
Personal protective equipment Respiratory protection
: Zircon-containing refractory coatings generally contain high levels of particles in the respirable fraction, but the potential for the inhalation of such particles is low when the product is handled in its liquid state. Manage inhalation exposure risks at those operations where dried refractory coatings may be- come airborne, such as spill residue cleanup operations, core touchup operations, shakeout operations, and spent sand handling and processing operations, through exhaust ventila- tion, exposure monitoring and, if needed, through use of res- piratory protection equipment. Respiratory protection is not typically required when ade- quate engineering and other workplace controls and a pro- gram of periodic worker exposure monitoring are provided. Use N100 "HEPA" respirators or supplied air systems where engineering and other workplace controls do not consistently control worker exposures to respirable crystalline silica to
6 / 22
SAFETY DATA SHEET
JetKote 400 Q
Version 2.0
Revision Date: 11/08/2022
SDS Number: V_0000019497
Date of last issue: - Date of first issue: 09/25/2020
below the OSHA or other applicable exposure criteria. Tight- fitting respirators must be fit-tested either qualitatively or quantitatively for each respirator user. Use only NIOSH- certified respirators. Where respirators are required, a respir- atory protection program shall be implemented in accordance with OSHA Standard 29 CFR §1910.134. ANSI Standard Z88.2 (current edition) "American National Standard for Res- piratory Protection" should also be considered.
Chemical cartridge respirators or supplied air systems are recommended where control of alcohol vapor is required.
Hand protection
Remarks
: Palm-dipped cotton work gloves are recommended for inci- dental contact and general core station use. For tasks involv- ing immersion or similar significant skin exposure use nitrile chemical handling gloves. : Ensure that eyewash stations and safety showers are close to the workstation location. Tightly fitting safety goggles : Personnel working in alcohol-based coating application areas should wear flame-resistant clothing and anti-static footwear. Provide splash and spray protection commensurate with the risks of exposure in your application. Launder work clothing frequently. Change work clothing after each work shift. : Wash hands before breaks and at the end of workday. Exposure monitoring for respirable particulate matter and the product solvent vapor may be warranted depending on the method of application and the amount of exhaust ventilation provided. Maintain respirable dust exposure levels below 2.8 mg/m3 to ensure the internal radiation dose will not exceed 10% of the Annual Limits on Intake (ALI) specified in 10 CFR 20.1502(b) and Nuclear Regulatory Commission (NRC) standards for protection against radiation for thorium, radium, and radioactive daughter decay products. Care should be taken to prevent inhalation exposures at those operations where dried refractory coatings may become airborne, such as spill residue cleanup operations, core touchup operations, shakeout operations, and spent sand handling and pro- cessing operations. Do not breathe over spray in coating spray applications. Zirconium sands and flours contain trace quantities of natu- rally occurring radioactive uranium, thorium and radium. Overexposure by inhalation to respirable dusts may cause lung cancer. Observance of the exposure limits for respirable dust (see Section 8) will ensure that the user is within limits established for exposure to naturally occurring radioactive uranium, thorium and radium.
Eye protection
Skin and body protection
Hygiene measures
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
: premix
Colour Odour
: blue
: alcohol-like
Odour Threshold
: No data available
7 / 22
SAFETY DATA SHEET
JetKote 400 Q
Version 2.0
Revision Date: 11/08/2022
SDS Number: V_0000019497
Date of last issue: - Date of first issue: 09/25/2020
pH
: No data available : No data available : 180 °F / 82 °C (Solvent)
Freezing point Boiling point
Flash point
: 54 °F / 12 °C
Method: closed cup (Solvent)
Evaporation rate
: No data available : No data available : No data available : No data available
Flammability (solid, gas) Flammability (liquids)
Self-ignition
Upper explosion limit / Upper flammability limit
: Upper flammability limit 12.7 %(V) (Solvent) : Lower flammability limit 2 %(V) (Solvent)
Lower explosion limit / Lower flammability limit
Vapour pressure
: 43 hPa (68 °F / 20 °C) (Solvent)
Relative vapour density
: 1
Relative density
: 1.94 - 2.01
Solubility(ies)
Water solubility : No data available Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity Viscosity, dynamic : 3,000 - 4,000 cP
SECTION 10. STABILITY AND REACTIVITY
Reactivity
: Not classified as a reactivity hazard.
Chemical stability
: Stable under recommended storage conditions. : No decomposition if stored and applied as directed. Vapours may form explosive mixture with air.
Possibility of hazardous reac- tions
Conditions to avoid Incompatible materials
: Heat, flames and sparks. : Strong acids, strong oxidizers
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity Not classified based on available information.
8 / 22
SAFETY DATA SHEET
JetKote 400 Q
Version 2.0
Revision Date: 11/08/2022
SDS Number: V_0000019497
Date of last issue: - Date of first issue: 09/25/2020
Components:
Isopropyl alcohol: Acute oral toxicity
: LD50 (Rat): 5.84 g/kg
Acute inhalation toxicity
: Lowest observed adverse effect level (Rat): 10000 ppm Exposure time: 6 h Test atmosphere: vapour
Acute dermal toxicity
: LD50 (Rabbit): 12,800 mg/kg
Rosin: Acute oral toxicity
: LD50 (Rat): > 5,000 mg/kg
Acute dermal toxicity
: LD50 (Rat): 2,500 mg/kg
Quartz (SiO2): Acute oral toxicity
: LD50 (Rat): 22,500 mg/kg
Titanium dioxide: Acute oral toxicity
: LD50 (Rat): > 11,000 mg/kg
Acute inhalation toxicity
: LC50 (Rat): 3.43 mg/l Exposure time: 4 h
Test atmosphere: Inhalation
Skin corrosion/irritation Not classified based on available information.
Components:
Isopropyl alcohol: Species
: Rabbit : 4 - 48 h
Exposure time Assessment
: Not classified
Rosin: Species
: Rabbit
Exposure time Assessment
: 24 - 72 h : Not irritant
Titanium dioxide: Species
: Rabbit
Exposure time Assessment
: 24 - 72 h : Not irritant
Serious eye damage/eye irritation Causes serious eye irritation.
9 / 22
SAFETY DATA SHEET
JetKote 400 Q
Version 2.0
Revision Date: 11/08/2022
SDS Number: V_0000019497
Date of last issue: - Date of first issue: 09/25/2020
Components:
Isopropyl alcohol: Species
: Rabbit
Exposure time Assessment
: 1 d
: Category 2: Causes serious eye irritation
Result
: irritating
Titanium dioxide: Species
: Rabbit
Exposure time Assessment
: 24 - 72 hrs : Not irritating
Respiratory or skin sensitisation
Skin sensitisation May cause an allergic skin reaction.
Respiratory sensitisation Not classified based on available information.
Components:
Isopropyl alcohol: Test Type
: Skin sensitization:
Species
: Guinea pig
Result
: Non sensitising
Rosin: Assessment
: May cause sensitisation by skin contact.
Titanium dioxide: Test Type
: Skin sensitization:
Species
: Guinea pig
Result
: Non sensitising
Germ cell mutagenicity Not classified based on available information.
Carcinogenicity May cause cancer. Inhalation exposure to radionuclides may cause cancer.
The contact dose rate from bulk quantities is in the order of 1 to 2μSv/h above the background. A person may work in dust concentrations of 3 mg/m3 for a full year with out exceeding the maximum dose for a worker. Respirable dust levels in typical zircon processing operations are reported in IAEA Safety Report No 51, and are less than 25% of the maximum dose to workers of 1 mSv/y (ICRP).
Components:
Quartz (SiO2): Carcinogenicity -
: Human carcinogen.
10 / 22
SAFETY DATA SHEET
JetKote 400 Q
Version 2.0
Revision Date: 11/08/2022
SDS Number: V_0000019497
Date of last issue: - Date of first issue: 09/25/2020
Assessment
Titanium dioxide: Carcinogenicity - Assessment
: Suspected human carcinogens
IARC
Group 1: Carcinogenic to humans Quartz (SiO2)
14808-60-7
(Silica dust, crystalline) Group 2B: Possibly carcinogenic to humans Titanium dioxide
13463-67-7
OSHA
OSHA specifically regulated carcinogen Quartz (SiO2)
14808-60-7
(crystalline silica)
NTP
Known to be human carcinogen Quartz (SiO2) (Silica, Crystalline (Respirable Size))
14808-60-7
Reproductive toxicity Not classified based on available information.
STOT - single exposure May cause drowsiness or dizziness.
Components:
Isopropyl alcohol: Assessment
: The substance or mixture is classified as specific target organ toxicant, single exposure, category 3 with narcotic effects.
STOT - repeated exposure Not classified based on available information.
Components:
Quartz (SiO2): Target Organs
: Lungs, Kidney, Autoimmune system
Assessment
: The substance or mixture is classified as specific target organ toxicant, repeated exposure, category 1.
Repeated dose toxicity
Components:
Isopropyl alcohol: Species
: Rat, male and female
NOAEL
: 5,000 ppm(m)
Application Route
: Inhalation
Exposure time
: >= 104 Weeks
Aspiration toxicity Not classified based on available information.
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SAFETY DATA SHEET
JetKote 400 Q
Version 2.0
Revision Date: 11/08/2022
SDS Number: V_0000019497
Date of last issue: - Date of first issue: 09/25/2020
Experience with human exposure
Components:
Quartz (SiO2): General Information
: Breathing silica dust may not cause noticeable injury or illness even though permanent lung damage may be occurring. Inhalation of dust may have serious chronic health effects (see below Repeat Dose Toxicity.) Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a progressive, disabling and sometimes fatal lung disease called silicosis. Symptoms include cough, shortness of breath, wheezing, non-specific chest illness and reduced pulmonary function. This disease is exacerbated by smoking. Inhalation of air with a very high concentration of respirable silica dust can cause the most serious forms of silicosis in a matter of months or a few years. Some epidemiologic studies have concluded that there is significant risk of developing silicosis even at airborne exposure levels that are equal to the recommended NIOSH REL, and ACGIH TLV. Silicosis can exist in several forms, chronic (or ordinary), accelerated, or acute. Chronic Silicosis. Chronic silicosis is the most common presentation of silicosis and usually occurs after at least 10 years of exposure to respirable crystalline silica. Symptoms- shortness of breath and cough, although employees may not notice any symptoms early in the disease. Constitutional symptoms, such as fever, loss of appetite and fatigue, may indicate other diseases associated with silica exposure, such as TB infection or lung cancer. Employees with these symptoms should immediately receive further evaluation and treatment. Accelerated Silicosis. Accelerated silicosis generally occurs within 5-10 years of exposure and results from high levels of exposure to respirable crystalline silica. Symptoms-shortness of breath, cough, and sometimes sputum production. Employees with exposure to respirable crystalline silica, and especially those with accelerated silicosis, are at high risk for activation of TB infections, atypical mycobacterial infections, and fungal superinfections. Constitutional symptoms, such as fever, weight loss, hemoptysis (coughing up blood), and fatigue may herald one of these infections or the onset of lung cancer. Clinical Course-accelerated silicosis has a rapid, severe course. Acute Silicosis. Acute silicosis is a rare disease caused by inhalation of extremely high levels of respirable crystalline silica particles. Acute silicosis develops rapidly, often within a few months to less than 2 years of exposure, and is almost always fatal. Symptoms-sudden, progressive, and severe shortness of breath. Constitutional symptoms are frequently present and include fever, weight loss, fatigue, productive cough, hemoptysis (coughing up blood), and pleuritic chest pain. Employees with acute silicosis are at especially high risk of TB
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SAFETY DATA SHEET
JetKote 400 Q
Version 2.0
Revision Date: 11/08/2022
SDS Number: V_0000019497
Date of last issue: - Date of first issue: 09/25/2020
activation, nontuberculous mycobacterial infections, and fungal superinfections. Acute silicosis is immediately life- threatening. COPD, including chronic bronchitis and emphysema, has been documented in silica-exposed employees, including those who do not develop silicosis. Heart disease may develop secondary to lung diseases such as COPD. A recent study by Liu et al. 2014 noted a significant exposure-response trend between cumulative silica exposure and heart disease deaths, primarily due to pulmonary heart disease, such as cor pulmonale. Renal and Immune System. Silica exposure has been associated with several types of kidney disease, including glomerulonephritis, nephrotic syndrome, and end stage renal disease requiring dialysis. Silica exposure has also been associated with other autoimmune conditions, including progressive systemic sclerosis, systemic lupus erythematosus, and rheumatoid arthritis. Studies note an association between employees with silicosis and serologic markers for autoimmune diseases, including antinuclear antibodies, rheumatoid factor, and immune complexes (Jalloul and Banks 2007; Shtraichman et al. 2015). TB and Other Infections. Silica exposed employees with latent TB are 3 to 30 times more likely to develop active pulmonary TB infection (ATS 1997; Rees and Murray 2007). Although respirable crystalline silica exposure does not cause TB infection, individuals with latent TB infection are at increased risk for activation of disease if they have higher levels of respirable crystalline silica exposure, greater profusion of radiographic abnormalities, or a diagnosis of silicosis. Additionally, silica-exposed employees are at increased risk for contracting nontuberculous mycobacterial infections, including Mycobacterium avium-intracellulare and Mycobacterium kansaii. Lung Cancer. The National Toxicology Program has listed respirable crystalline silica as a known human carcinogen since 2000 (NTP 2014). The International Agency for Research on Cancer (2012) has also classified silica as Group 1 (carcinogenic to humans). Several studies have indicated that the risk of lung cancer from exposure to respirable crystalline silica and smoking is greater than additive (Brown 2009; Liu et al. 2013). Other Data with Possible Relevance to Human Health: There is some evidence that breathing respirable crystalline silica or the disease silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder manifested by fibrosis of the lungs, skin and other internal organs) rheumatoid arthritis, systemic lupus, erythematosus, sarcoidosis, chronic bronchitis, chronic obstructive pulmonary disease (COPD), emphysema, chronic kidney disease and end-stage renal disease. Medical Conditions Generally Aggravated by Exposure: The condition of individuals with existing respiratory system disease(s) (e.g., bronchitis, emphysema, chronic obstructive pulmonary disease) and/or dysfunctions can be aggravated by
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SAFETY DATA SHEET
JetKote 400 Q
Version 2.0
Revision Date: 11/08/2022
SDS Number: V_0000019497
Date of last issue: - Date of first issue: 09/25/2020
exposure. Exposure to dust may aggravate existing skin and/or eye conditions. Smoking and obstructive/restrictive lung diseases may also exacerbate the effects of excessive exposure to this product. For further information consult "Adverse Effects of Crystalline Silica Exposure" published by the American Thoracic Society Medical Section of the American Lung Association, American Journal of Respiratory and Critical Care Medicine, Volume 155, pages 761-768, 1997, and see also NIOSH Hazard Review – Health Effects of Occupational Exposure to Respirable Crystalline Silica, April 2002 (see Section 7 for NIOSH Hazard Review Website)
Further information
Product : Remarks
: Solvent exposure can cause skin de-fatting, leading to irritation, dry skin, and skin cracking which can become severe. This effect is temporary if the exposure ceases.
Components:
Quartz (SiO2): Remarks
: There have been many articles published on the carcinogenicity of crystalline silica, which the reader and any user should consult for additional information; the following are examples of recently published articles: (1) "Dose- Response Meta- Analysis of Silica and Lung Cancer", Cancer Causes Control, (20):925-33 (2009); (2) "Occupational Silica Exposure and Lung Cancer Risk: A Review of Epidemiological Studies 1996-2005', Ann Oncol, (17) 1039-50 (2006); (3) "Lung Cancer Among Industrial Sand Workers Exposed to Crystalline Silica", Am J Epidemiol, (153) 695-703 (2001); (4) "Crystalline Silica and The Risk of Lung Cancer in The Potteries", Occup Environ Med, (55) 779-785 (1998); (5) "Is Silicosis Required for Silica-Associated Lung Cancer?", American Journal of Industrial Medicine, (37) 252- 259 (2000); (6) "Silica, Silicosis, and Lung Cancer: A Risk Assessment", American Journal of Industrial Medicine, (38) 8-18 (2000); (7) "Silica, Silicosis, and Lung Cancer: A Response to a Recent Working Group Report", Journal of Occupational and Environmental Medicine, (42) 704-720 (2000).
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Components:
Isopropyl alcohol: Toxicity to fish
: LC50 (Pimephales promelas (fathead minnow)): 9,640 mg/l Exposure time: 96 h
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SAFETY DATA SHEET
JetKote 400 Q
Version 2.0
Revision Date: 11/08/2022
SDS Number: V_0000019497
Date of last issue: - Date of first issue: 09/25/2020
Toxicity to daphnia and other aquatic invertebrates
: LC50 (Crangon crangon (shrimp)): 900 - 1,950 mg/l Exposure time: 48 h
Rosin:
Ecotoxicology Assessment Chronic aquatic toxicity
: Toxic to aquatic life with long lasting effects.
Quartz (SiO2): Toxicity to daphnia and other aquatic invertebrates
: LC50 (Daphnia magna (Water flea)): 10,000 mg/l Exposure time: 24 h
Titanium dioxide: Toxicity to fish
: LC50 (Fundulus heteroclitus): > 1,000 mg/l Exposure time: 96 h
Toxicity to daphnia and other aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): > 1,000 mg/l Exposure time: 48 h
Persistence and degradability
Components:
Isopropyl alcohol: Biodegradability
: Inoculum: sewage, domestic (adaptation not specified) O2 consumption Biodegradation: 53 % Exposure time: 5 d
Bioaccumulative potential
Components:
Isopropyl alcohol: Partition coefficient: n- octanol/water
: log Pow: 0.05
Rosin: Bioaccumulation
: Species: Oncorhynchus mykiss (rainbow trout) Bioconcentration factor (BCF): 69 Exposure time: 20 d Temperature: 59 °F / 15 °C Concentration: 2.1 µg/l
Partition coefficient: n- octanol/water
: log Pow: > 1.9 - 7.7 pH: 2
Titanium dioxide: Bioaccumulation
: Species: Oncorhynchus mykiss (rainbow trout) Bioconcentration factor (BCF): 58 Exposure time: 14 d Temperature: 57 °F / 14 °C
15 / 22
SAFETY DATA SHEET
JetKote 400 Q
Version 2.0
Revision Date: 11/08/2022
SDS Number: V_0000019497
Date of last issue: - Date of first issue: 09/25/2020
Concentration: 0.5 mg/l
Mobility in soil No data available
Other adverse effects
Product: Ozone-Depletion Potential
: Regulation: 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks: This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
Additional ecological information
: No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal advice Waste from residues
: The NORM (naturally-occurring radioactive material) content of this product may activate radiation detection sensors in place at some scrap metal processing and waste disposal sites, ports, and other transportation infrastructure facilities. Zircon in this product is exempt from NRC regulations for source material at 10 CFR 40.13(b) since it falls under the definition of unprocessed materials containing less than 0.05% uranium or thorium. Check local and state regulations regarding NORM to determine any additional requirements potentially applicable to the use, handling or disposal of this product. Do not dispose into sewers or waterways. Unused product and liquid container residues are ignitable (D001) hazardous waste. Radionuclide content may require testing or trigger disposal prohibitions at some facilities, and may trigger radia- tion safety devices commonly used at disposal sites. Notify proposed disposal facilities of the radionuclide content, alco- hol content and flash point of the product during waste profil- ing. Dried product residues are not typically ignitable. : Dispose of contents and containers to an approved waste disposal plant. Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum.
Contaminated packaging
SECTION 14. TRANSPORT INFORMATION
National Regulations
16 / 22
SAFETY DATA SHEET
JetKote 400 Q
Version 2.0
Revision Date: 11/08/2022
SDS Number: V_0000019497
Date of last issue: - Date of first issue: 09/25/2020
49 CFR UN/ID/NA number
: UN 1139
Proper shipping name
: Coating solution
Class
: 3 : II
Packing group
Labels
: FLAMMABLE LIQUID
ERG Code
: 127
Marine pollutant
: no
Special precautions for user The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and var- iations in regional or country regulations.
International Regulations
UNRTDG UN number
: UN 1139
Proper shipping name
: COATING SOLUTION
Class
: 3 : II : 3
Packing group
Labels
IATA-DGR UN/ID No.
: UN 1139
Proper shipping name
: Coating solution
Class
: 3 : II
Packing group
Labels
: Flammable Liquids
Packing instruction (cargo aircraft) Packing instruction (passen- ger aircraft)
: 364
: 353
IMDG-Code UN number
: UN 1139
Proper shipping name
: COATING SOLUTION
Class
: 3 : II : 3
Packing group
Labels
EmS Code
: F-E, S-E
Marine pollutant
: no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied.
SECTION 15. REGULATORY INFORMATION
CERCLA Reportable Quantity CERCLA Reportable Quantity (RQ) for radionuclides at 40 C.F.R. 302.4 Appendix B lists RQ for U (natural) at 1 E11 pCi (3.7E9 Bq) and Th (natural) at 1 E 10 pCi (3.7 E7 Bq). RQ reporting for these constituents would be triggered by the “release” of 18,000 pounds of zircon in a 24-hour pe- riod.
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SAFETY DATA SHEET
JetKote 400 Q
Version 2.0
Revision Date: 11/08/2022
SDS Number: V_0000019497
Date of last issue: - Date of first issue: 09/25/2020
SARA 304 Extremely Hazardous Substances Reportable Quantity None present above reporting thresholds.
SARA 302 Extremely Hazardous Substances Threshold Planning Quantity This material does not contain any components with a section 302 EHS TPQ.
SARA 311/312 Hazards
: Flammable (gases, aerosols, liquids, or solids) Respiratory or skin sensitisation Carcinogenicity Serious eye damage or eye irritation Specific target organ toxicity (single or repeated exposure)
SARA 313
: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Clean Air Act This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 112 (40 CFR 61): Zircon Sand and Flour Radionuclides Not Assigned < 500 PPM This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). Clean Water Act This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3. This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 This product does not contain any priority pollutants related to the U.S. Clean Water Act
US State Regulations
Massachusetts Right To Know Isopropyl alcohol
67-63-0
Quartz (SiO2)
14808-60-7
Pennsylvania Right To Know Zircon
14940-68-2
Isopropyl alcohol Aluminium oxide
67-63-0
1344-28-1
Maine Chemicals of High Concern Quartz (SiO2) Vermont Chemicals of High Concern Formaldehyde Washington Chemicals of High Concern Formaldehyde
14808-60-7
50-00-0
50-00-0
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