Geochemistry Guide 2026

Exploration analysis

Aqua regia digestion Aqua regia is a combination of hydrochloric and nitric acids in a nominal 3:1 ratio. This is a weak digestion for geological samples that is appropriate for initial site exploration. Aqua regia will not break down silicate and other refractory minerals, providing partial results for most elements. ICP-OES, ICP-MS or a combination of both techniques can be used to measure these digests. For samples containing high levels of organic matter or sulphide minerals, a modified aqua regia method (GE_ICP22B20 and/or GE_IMS22B20) is recommended. Instrumentation ICP-OES and ICP-MS are accepted in the mineral exploration industry as rapid and cost- effective means of analysis, because they determine many elements at low detection limits and wide ranges. Other instruments that can be used for specific elements are AAS (Atomic Absorption Spectrophotometer) and Hydride AAS.

GE_ICP21B20 AQUA REGIA DIGESTION / ICP-OES PACKAGE Ag 2 - 100 ppm Hg

Sb Sc Sn

1 - 10,000 ppm

5 - 10,000 ppm 0.5 - 10,000 ppm 10 - 10,000 ppm 0.5 - 10,000 ppm

K

AI

0.005 - 15%

0.005 - 15%

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La

As 3 - 10,000 ppm Ba 2 - 10,000 ppm Be 0.5 - 2,500 ppm

0.5 - 10,000 ppm 1 - 10,000 ppm

Li

Sr

Mg Mn Mo

Ti

0.001 - 15%

0.001 - 15%

V

Bi

5 - 10,000 ppm

2 - 10,000 ppm 1 - 10,000 ppm

1 - 10,000 ppm 10 - 10,000 ppm 0.5 - 10,000 ppm

W

Ca 0.002 - 15% Cd 1 - 10,000 ppm Co 1 - 10,000 ppm

Na

Y

0.005 - 15%

Ni

Zn 1- 10,000 ppm

1 - 10,000 ppm

P

0.003 - 15%

Zr

Cr

1 - 10,000 ppm

0.5 - 10,000 ppm

Pb

Cu 0.5 - 10,000 ppm

2 - 10,000 ppm

Fe

S

0.01 - 15%

0.01 - 5%

Additional elements can be added upon request.

GE_IMS21B20 AQUA REGIA DIGESTION / ICP-MS PACKAGE Ag 0.01 - 10 ppm Ga

Multi-element exploration ICP-OES and ICP-MS packages

Sc Sn Sr Th Ti TI U V W

0.1 - 10,000 ppm 0.01 - 100 ppm

0.1 - 10,000 ppm 0.2 - 1,000 ppm 0.5 - 10,000 ppm 0.05 - 10,000 ppm

Hg

AI

0.01 - 10%

K

As 1 - 10,000 ppm Ba 5 - 10,000 ppm Be 0.05 - 100 ppm

0.01 - 10%

Sample digestion Sample digestion is one of the most important parameters to consider when choosing an analytical method. There are several types of digestion available, including:

La

0.1 - 10,000 ppm

Mg Mn Mo

0.01 - 15%

0.01 - 10%

Bi

0.01 - 10,000 ppm

2 - 10,000 ppm

0.02 - 10,000 ppm 0.05 - 10,000 ppm

Ca 0.01 - 15%

0.05 - 10,000 ppm

• Aqua regia digestion • Four acid digestion • Sodium peroxide fusion • Lithium metaborate fusion

Na

Cd 0.01 - 10,000 ppm Ce 0.02 - 1,000 ppm Co 0.1 - 10,000 ppm

0.01 - 10%

1 - 10,000 ppm

Ni

0.2- 10,000 ppm

0.05 - 10,000 ppm 0.05 - 10,000 ppm

P

Y

0.01 - 1%

Pb Rb Sb

Zn

Cr

1 - 10,000 ppm 0.5 - 10,000 ppm

0.2 - 10,000 ppm 0.05 - 10,000 ppm 0.05 - 10,000 ppm

1 - 10,000 ppm

Cu Fe

0.01 - 15%

Typically, reconnaissance exploration grade samples (including regional soil samples) are analyzed by aqua regia digestion followed by a multi-element scan for base metals, trace and lithological elements. Drill-core and rock samples are generally analyzed by four acid or fusion digestion, with a multi- element finish. Where metal contents are high, samples can require further testing by other methods to ensure data is precise and accurate enough for regulatory reporting. Refer to the Ore-Grade Analysis section in this guide.

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