LGC AXIO Proficiency Testing | Food Supplements

Food Supplements: moving from the ‘Wild West’ towards quality and compliance

In this unique PT sample, AXIO has provided a means for laboratories to assess the compliance of a supplement product with the claims or information provided on the label. Proficiency testing can help laboratories assess compliance with labelling

Sample

Quantity Supplied as

Target Analyte(s)

PT-PH-21 Potency of multielement

15g

Multielement supplement

Calcium; Zinc; Magnesium; Copper; Manganese; Potassium; Iron; Total Chromium; Selenium; Compliance with labelling.

It challenges laboratories to decide whether they would consider the product compliant or not, based on the label provided in the instruction sheet, their obtained testing results (including the uncertainty of measurement) and the guidance documents. The PT summary results for two analytes, zinc and potassium (respectively labelled at 5.882 and 0.046 mg/g on the provided label), are shown below.

Standard deviation for proficiency assessment (SDPA)

Uncertainty of Assigned Value

Satisfactory Range 4.78 to 6.89 0.34 to 1.06

Analyte

Unit

Assigned Value

Exp. SDPA

Zinc

mg/g 5.84

0.213 0.072

0.482 0.163

0.527 0.178

Potassium mg/g 0.70

The satisfactory range in a proficiency testing exercise is derived from the Assigned Value and the standard deviation for proficiency assessment (SDPA). In many cases the satisfactory range for proficiency testing is defined as the assigned value +/- 2 times the SDPA. The measurement uncertainty of the assigned value is included in the estimation of the satisfactory range. The EU guidance document on the control of compliance for minerals in food supplements specifies lower and upper tolerances (including the measurement of uncertainty for the analytical result) of -20% and +45% respectively.

PROFICIENCY TESTING

LABEL

Acceptable range based on the guidance document of -20%, +45%

Satisfactory range in the PT

Assigned value (AV)

Label (mg per g)

Element

Lower limit

Upper limit

Lower limit

Upper limit

5.84

4.78 0.34

6.89 1.06

5.882 0.027

4.706 0.022

8.529 0.039

Zinc

Potassium 0.7

Zinc concentration was compliant with the labelling, as the measured result and its uncertainty overlap significantly with the label value and its tolerances, while the potassium concentration was not.

9

Assigned Value Min/Max range

8

7

6

5

4

3

2

1

0

Zn Data

Zn Label

K Data

K Label

6

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